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题名: Enantioselective Synthesis of Endocyclic beta-Amino Acids with Two Contiguous Stereocenters via Hydrogenation of 3-Alkoxycarbonyl-2-Substituted Quinolines
作者: Chen, Zhang-Pei1;  Ye, Zhi-Shi1;  Chen, Mu-Wang1;  Zhou, Yong-Gui1
关键词: beta-amino acids ;  iridium ;  asymmetric hydrogenation ;  functionalized quinolines
刊名: SYNTHESIS-STUTTGART
发表日期: 2013-12-02
DOI: 10.1055/s-0033-1339849
卷: 45, 期:23, 页:3239-3244
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An enantioselective iridium-catalyzed hydrogenation of 3-alkoxycarbonyl-2-substituted quinoline derivatives is described. This methodology provides a convenient route to enantiopure endocyclic -amino acids with two contiguous stereocenters with up to 90% ee.
关键词[WOS]: IRIDIUM-CATALYZED HYDROGENATION ;  IR-F-BINAPHANE ;  ASYMMETRIC HYDROGENATION ;  HETEROAROMATIC-COMPOUNDS ;  ADDITION-CYCLIZATION ;  REDUCTIVE AMINATION ;  DERIVATIVES ;  PYRIDINES ;  PEPTIDES ;  STRATEGY
语种: 英语
WOS记录号: WOS:000327193900007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137806
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Chen, Zhang-Pei,Ye, Zhi-Shi,Chen, Mu-Wang,et al. Enantioselective Synthesis of Endocyclic beta-Amino Acids with Two Contiguous Stereocenters via Hydrogenation of 3-Alkoxycarbonyl-2-Substituted Quinolines[J]. SYNTHESIS-STUTTGART,2013,45(23):3239-3244.
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