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题名: Asymmetric Epoxidation of Alkenes Catalyzed by a Porphyrin-Inspired Manganese Complex
作者: Dai, Wen1, 2, 3;  Li, Jun1, 2;  Li, Guosong1, 2;  Yang, Hua1, 2, 3;  Wang, Lianyue1, 2;  Gao, Shuang1, 2
刊名: ORGANIC LETTERS
发表日期: 2013-08-16
DOI: 10.1021/ol401812h
卷: 15, 期:16, 页:4138-4141
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A novel strategy for catalytic asymmetric epoxidation of a wide variety of olefins by a porphyrin-inspired chiral manganese complex using H2O2 as a terminal oxidant in excellent yield with up to greater than 99% ee has been successfully developed.
关键词[WOS]: AQUEOUS HYDROGEN-PEROXIDE ;  ENANTIOSELECTIVE EPOXIDATION ;  UNFUNCTIONALIZED OLEFINS ;  OXIDATION CATALYSIS ;  TERMINAL OLEFINS ;  CYCLOPROPANATION ;  OXIDANT ;  KETONES
语种: 英语
WOS记录号: WOS:000323363100025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137827
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Dai, Wen,Li, Jun,Li, Guosong,et al. Asymmetric Epoxidation of Alkenes Catalyzed by a Porphyrin-Inspired Manganese Complex[J]. ORGANIC LETTERS,2013,15(16):4138-4141.
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