DICP OpenIR
Effects of Al-based additives on the hydrogen storage performance of the Mg(NH2)(2)-2LiH system
Cao, Hujun1,2,3; Zhang, Yao1; Wang, Jianhui1; Xiong, Zhitao1; Wu, Guotao1; Qiu, Jieshan2; Chen, Ping1,4
刊名DALTON TRANSACTIONS
2013
DOI10.1039/c3dt32165g
42期:15页:5524-5531
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]N-H SYSTEM ; THERMAL-DECOMPOSITION ; CRYSTAL-STRUCTURE ; LI ; DESORPTION ; ABSORPTION ; HYDRIDE ; LIBH4 ; LIAL(NH2)(4) ; IMPROVEMENT
英文摘要The Mg(NH2)(2)-2LiH composite is a promising hydrogen storage material due to its relatively high reversible hydrogen capacity (similar to 5.6 wt%) and suitable thermodynamic properties that allow hydrogen sorption conducting at temperatures below 90 degrees C. However, the presence of a severe kinetic barrier inhibits its low-temperature operation. In the present work, Li3AlH6 was introduced to the Mg(NH2)(2)-2LiH system. Experimental results show that a 3.2% mol Li3AlH6-modified Mg(NH2)(2)-2LiH sample released hydrogen at a rate ca. 4.5 times as fast as that of the Li3AlH6-free sample at 140 degrees C. The enhancement of desorption kinetics was simultaneously demonstrated by activation energy (E-a) of ca. 96.3 +/- 9 kJ mol(-1) which was significantly decreased by 31 kJ mol(-1) from that of the Li3AlH6-free sample. The interaction of Li3AlH6 and Mg(NH2)(2) during ball milling results in the formation of LiAl(NH)(2), LiNH2 and Mg3N2. LiAl(NH)(2) was actually the active species for the enhancement of dehydrogenation/re-hydrogenation kinetics of the system.
语种英语
WOS记录号WOS:000316300700040
引用统计
被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137849
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Carbon Res Lab, Liaoning Key Lab Energy Mat & Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Int Inst Carbon Neutral Energy Res I2CNER, Nishi Ku, Fukuoka 8190395, Japan
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GB/T 7714
Cao, Hujun,Zhang, Yao,Wang, Jianhui,et al. Effects of Al-based additives on the hydrogen storage performance of the Mg(NH2)(2)-2LiH system[J]. DALTON TRANSACTIONS,2013,42(15):5524-5531.
APA Cao, Hujun.,Zhang, Yao.,Wang, Jianhui.,Xiong, Zhitao.,Wu, Guotao.,...&Chen, Ping.(2013).Effects of Al-based additives on the hydrogen storage performance of the Mg(NH2)(2)-2LiH system.DALTON TRANSACTIONS,42(15),5524-5531.
MLA Cao, Hujun,et al."Effects of Al-based additives on the hydrogen storage performance of the Mg(NH2)(2)-2LiH system".DALTON TRANSACTIONS 42.15(2013):5524-5531.
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