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Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage
Liu, Lin; Hu, Daqiang; He, Teng; Zhang, Yao; Wu, Guotao; Chu, Hailiang; Wang, Peikun; Xiong, Zhitao; Chen, Ping
关键词Chemical Hydrogen Storage Lithium BoroHydride-melamine Complex Hydride Protic Hydrogen Hydridic Hydrogen
刊名JOURNAL OF ALLOYS AND COMPOUNDS
2013-03-05
DOI10.1016/j.jallcom.2012.09.100
552页:98-101
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
研究领域[WOS]Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
关键词[WOS]DEHYDROGENATION BEHAVIOR ; LIBH4 ; DESTABILIZATION ; COMPOSITES ; AL ; REVERSIBILITY ; STABILITY ; POWDER ; MGH2 ; B-11
英文摘要A complex hydride, 3LiBH(4)center dot C3N6H6, crystallizing in monoclinic structure with lattice parameters of a = 17.4701 angstrom, b = 17.6332 angstrom, c = 4.1749 angstrom, beta = 99.7453 degrees and V = 1267.54 angstrom(3), was synthesized by solid reaction between LiBH4 and C3N6H6. 3LiBH(4)center dot C3N6H6 starts to evolve hydrogen at 100 degrees C, which is 190 degrees C lower than that of pristine LiBH4. Combination of protic hydrogen of [BH4](-) and hydridic hydrogen of NH in 3LiBH(4)center dot C3N6H6 may greatly improve the dehydrogenation properties, and totally 7.83 wt.% H-2 can be released from 3LiBH(4)center dot C3N6H6 in the temperature range of 100-340 degrees C. (C0 2012 Elsevier B. V. All rights reserved.
语种英语
WOS记录号WOS:000313653300017
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137853
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clear Energy, Dalian 116023, Peoples R China
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Liu, Lin,Hu, Daqiang,He, Teng,et al. Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2013,552:98-101.
APA Liu, Lin.,Hu, Daqiang.,He, Teng.,Zhang, Yao.,Wu, Guotao.,...&Chen, Ping.(2013).Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage.JOURNAL OF ALLOYS AND COMPOUNDS,552,98-101.
MLA Liu, Lin,et al."Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage".JOURNAL OF ALLOYS AND COMPOUNDS 552(2013):98-101.
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