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题名: Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage
作者: Liu, Lin1;  Hu, Daqiang1;  He, Teng1;  Zhang, Yao1;  Wu, Guotao1;  Chu, Hailiang1;  Wang, Peikun1;  Xiong, Zhitao1;  Chen, Ping1
关键词: Chemical hydrogen storage ;  Lithium borohydride-melamine complex hydride ;  Protic hydrogen ;  Hydridic hydrogen
刊名: JOURNAL OF ALLOYS AND COMPOUNDS
发表日期: 2013-03-05
DOI: 10.1016/j.jallcom.2012.09.100
卷: 552, 页:98-101
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Physical ;  Materials Science, Multidisciplinary ;  Metallurgy & Metallurgical Engineering
研究领域[WOS]: Chemistry ;  Materials Science ;  Metallurgy & Metallurgical Engineering
英文摘要: A complex hydride, 3LiBH(4)center dot C3N6H6, crystallizing in monoclinic structure with lattice parameters of a = 17.4701 angstrom, b = 17.6332 angstrom, c = 4.1749 angstrom, beta = 99.7453 degrees and V = 1267.54 angstrom(3), was synthesized by solid reaction between LiBH4 and C3N6H6. 3LiBH(4)center dot C3N6H6 starts to evolve hydrogen at 100 degrees C, which is 190 degrees C lower than that of pristine LiBH4. Combination of protic hydrogen of [BH4](-) and hydridic hydrogen of NH in 3LiBH(4)center dot C3N6H6 may greatly improve the dehydrogenation properties, and totally 7.83 wt.% H-2 can be released from 3LiBH(4)center dot C3N6H6 in the temperature range of 100-340 degrees C. (C0 2012 Elsevier B. V. All rights reserved.
关键词[WOS]: DEHYDROGENATION BEHAVIOR ;  LIBH4 ;  DESTABILIZATION ;  COMPOSITES ;  AL ;  REVERSIBILITY ;  STABILITY ;  POWDER ;  MGH2 ;  B-11
语种: 英语
WOS记录号: WOS:000313653300017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137853
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clear Energy, Dalian 116023, Peoples R China

Recommended Citation:
Liu, Lin,Hu, Daqiang,He, Teng,et al. Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2013,552:98-101.
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