中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: 1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period
作者: Li, Xiujie1;  Zhu, Xiangxue1;  Zhang, Dazhou1;  Chen, Fucun1;  Zeng, Peng2;  Liu, Shenglin1;  Xie, Sujuan1;  Xu, Longya1
关键词: 1-butene ;  metathesis ;  propene ;  molybdenum ;  production distribution ;  induction period
刊名: JOURNAL OF ENERGY CHEMISTRY
发表日期: 2013
卷: 22, 期:1, 页:145-150
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Energy & Fuels ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Energy & Fuels ;  Engineering
英文摘要: Effects of space velocity, reaction temperature and support acidity on product distribution and induction period in 1-butene isomerization and metathesis over Mo/mordenite-alumina were investigated. As revealed by the catalytic performance results, induction period and objective product were closely related to the reaction conditions. Lower space velocity led to longer induction period and higher propene yield. The optimal reaction temperature for propene production is around 150 degrees C and it shifted to 100 degrees C for ethene production. 1-Butene auto-metathesis predominated in the reaction network if the support with lower degree of sodium exchanged. And propene gradually became the dominant product upon increasing the support sodium exchange degree. 6Mo/H100Na0M-30Al catalyst with a support of full sodium exchange degree exhibited the highest propene yield.
关键词[WOS]: RHENIUM OXIDE CATALYSTS ;  OLEFIN METATHESIS ;  HETEROGENEOUS CATALYSTS ;  TUNGSTEN-OXIDE ;  PROPENE ;  2-BUTENE ;  ETHENE ;  PERFORMANCE ;  CRACKING ;  ALKENES
语种: 英语
WOS记录号: WOS:000318050700020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137859
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.China Huanqiu Contracting & Engn Corp, Liaoning Branches, Fushun 113006, Liaoning, Peoples R China

Recommended Citation:
Li, Xiujie,Zhu, Xiangxue,Zhang, Dazhou,et al. 1-Butene isomerization and metathesis over Mo/mordenite-alumina: Factors influencing product distribution and induction period[J]. JOURNAL OF ENERGY CHEMISTRY,2013,22(1):145-150.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li, Xiujie]'s Articles
 [Zhu, Xiangxue]'s Articles
 [Zhang, Dazhou]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li, Xiujie]‘s Articles
 [Zhu, Xiangxue]‘s Articles
 [Zhang, Dazhou]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace