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题名: Thermodynamic Properties of a New Hydrophobic Amide-Based Task-Specific Ionic Liquid [EimCH(2)CONHBu][NTf2]
作者: Liu, Qing-Shan1, 2;  Li, Zhuo3;  Welz-Biermann, Urs2;  Li, Chang-Ping4;  Liu, Xiao-Xia1
刊名: JOURNAL OF CHEMICAL AND ENGINEERING DATA
发表日期: 2013
DOI: 10.1021/je301001g
卷: 58, 期:1, 页:93-98
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Density, surface tension, dynamic viscosity, and electrical conductivity of a new air and water stable hydrophobic amide-based task-specific ionic liquid (IL) 1-butylamide-3-ethylimimdazolium bis-(trifluoromethylsulfonyl)imide ([EimCH(2)CONHBu] [NTf2]) were determined in the temperature range of T = (283 to 363) K. The volumetric and surface properties were discussed using the density and surface tension values. The thermal expansion coefficient was predicted by the interstice model theory. The decomposition temperature was determined with the thermogravimatric analysis (TG). The molar conductivity data were calculated by density and electrical conductivity values. Temperature dependence on dynamic viscosity and electrical conductivity values of the [EimCH(2)CONHBu][NTf2] were fitted by the VFT equation. The Arrhenius equation was also used to fit the dynamic viscosity and electrical conductivity values.
关键词[WOS]: PHYSICOCHEMICAL PROPERTIES ;  PHYSICAL-PROPERTIES ;  POTENTIAL ELECTROLYTES ;  SURFACE TENSIONS ;  VISCOSITY ;  DENSITY ;  CONDUCTIVITY ;  EXTRACTION ;  MIXTURES ;  PURE
语种: 英语
WOS记录号: WOS:000313220900013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137862
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Northeastern Univ, Dept Chem, Shenyang 110819, Peoples R China
2.Chinese Acad Sci, China Ion Liquid Lab, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Dalian Ocean Univ, Sch Sci, Dalian 116023, Peoples R China
4.Dalian Univ, Dept Chem Engn, Dalian 116622, Peoples R China

Recommended Citation:
Liu, Qing-Shan,Li, Zhuo,Welz-Biermann, Urs,et al. Thermodynamic Properties of a New Hydrophobic Amide-Based Task-Specific Ionic Liquid [EimCH(2)CONHBu][NTf2][J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2013,58(1):93-98.
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