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Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate
Zhong, Wen-Wen1; Di, You-Ying1; Tan, Zhi-Cheng2,3; Dou, Jian-Min1
关键词Crystal Structure Nickel Hydrogen Pyridine-2 Low-temperature Heat Capacity 6-dicarboxylate Trihydrate Thermodynamic Function Standard Molar Enthalpy Of Formation
刊名THERMOCHIMICA ACTA
2013-05-20
DOI10.1016/j.tca.2013.03.007
560页:27-33
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]TEMPERATURE HEAT-CAPACITIES ; STANDARD MOLAR ENTHALPY ; CHLORIDE
英文摘要Nickel hydrogen pyridine-2,6-dicarboxylate trihydrate (Ni(HDPC)(2)center dot 3H(2)O) was synthesized by the method of liquid phase synthesis. The composition and crystal structure of the complex were determined by chemical analysis, elemental analysis, and X-ray crystallography. Low-temperature heat capacities of the complex were measured over the temperature range from 78 to 353 K. Smoothed molar heat capacities and thermodynamic functions of the complex relative to the standard reference temperature 298.15 K were calculated based on the fitted polynomial equation. A reasonable thermochemical cycle was designed, and the standard molar enthalpies of dissolution for the reactants and products of the synthesis reaction in a selected solvent were measured. Eventually, the standard molar enthalpy of formation of the title complex was derived to be -(2467.9 +/- 3.2) kJ mol(-1) in accordance with Hess's law. (C) 2013 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000319175200005
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137933
专题中国科学院大连化学物理研究所
作者单位1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
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Zhong, Wen-Wen,Di, You-Ying,Tan, Zhi-Cheng,et al. Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate[J]. THERMOCHIMICA ACTA,2013,560:27-33.
APA Zhong, Wen-Wen,Di, You-Ying,Tan, Zhi-Cheng,&Dou, Jian-Min.(2013).Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate.THERMOCHIMICA ACTA,560,27-33.
MLA Zhong, Wen-Wen,et al."Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate".THERMOCHIMICA ACTA 560(2013):27-33.
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