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题名: Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide
作者: Yang, Xiaomei1;  Tang, Si1;  Lu, Tianliang1;  Chen, Chen2;  Zhou, Lipeng1;  Su, Yunlai1;  Xu, Jie2
关键词: Aldehydes ;  carboxylic acids ;  hydrogen peroxide ;  oxidation ;  sulfonic acid resin
刊名: SYNTHETIC COMMUNICATIONS
发表日期: 2013-03-01
DOI: 10.1080/00397911.2011.617487
卷: 43, 期:7, 页:979-985
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Oxidation of benzaldehyde to benzoic acid can be performed efficiently with 30% H2O2 as the oxidant and sulfonic acid resin Amberlyst 15 as the catalyst. The reactivities of benzaldehyde derivatives are determined by both hindrance effect and electron effect of substituents, and benzaldehyde derivatives with electron-withdrawing group at the meta- or para-position are highly active and almost quantitatively converted into their corresponding acids. In addition, this method also works well for the oxidation of aliphatic aldehydes. The key characteristic of the procedure is that the catalyst is recyclable.
关键词[WOS]: AROMATIC-ALDEHYDES ;  SELECTIVE OXIDATION ;  ORGANIC-SOLVENT
语种: 英语
WOS记录号: WOS:000313418700006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137980
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China
2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yang, Xiaomei,Tang, Si,Lu, Tianliang,et al. Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide[J]. SYNTHETIC COMMUNICATIONS,2013,43(7):979-985.
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