DICP OpenIR
Structure of Au-4(0/-1) in the gas phase: A joint geometry relaxed ab initio calculations and vibrationally resolved photoelectron imaging investigation
Liu, Zhiling; Qin, Zhengbo; Xie, Hua; Cong, Ran; Wu, Xia; Tang, Zichao
刊名JOURNAL OF CHEMICAL PHYSICS
2013-09-07
DOI10.1063/1.4819789
139期:9
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]ANIONIC GOLD CLUSTERS ; THEORETICAL CHEMISTRY ; ELECTRONIC-PROPERTIES ; METAL-CLUSTERS ; DENSITY ; SPECTROSCOPY ; NANOCLUSTERS ; SPECTRA ; PLANAR ; POTENTIALS
英文摘要We have combined photoelectron velocity-map imaging spectroscopy and high-level ab initio calculations to elucidate the geometries of Au-4(0/-1). Well-resolved ground-state electronic transition was observed in the photoelectron spectrum of Au-4 at 446 nm, leading to more accurate electron affinity and vibrational frequencies for the ground state of the neutral Au-4 . The pure and vibrationally resolved spectra provide definitive experimental evidence for the resolution of the ground-state gold tetramer in the gaseous phase, with the aid of the ab initio calculations and Franck-Condon simulations. The comprehensive comparisons between the experiment and theoretical calculations suggest that the Y-shaped structure is the global minimum for both the neutral and anionic Au-4. (C) 2013 AIP Publishing LLC.
语种英语
WOS记录号WOS:000324378400025
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137984
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Liu, Zhiling,Qin, Zhengbo,Xie, Hua,et al. Structure of Au-4(0/-1) in the gas phase: A joint geometry relaxed ab initio calculations and vibrationally resolved photoelectron imaging investigation[J]. JOURNAL OF CHEMICAL PHYSICS,2013,139(9).
APA Liu, Zhiling,Qin, Zhengbo,Xie, Hua,Cong, Ran,Wu, Xia,&Tang, Zichao.(2013).Structure of Au-4(0/-1) in the gas phase: A joint geometry relaxed ab initio calculations and vibrationally resolved photoelectron imaging investigation.JOURNAL OF CHEMICAL PHYSICS,139(9).
MLA Liu, Zhiling,et al."Structure of Au-4(0/-1) in the gas phase: A joint geometry relaxed ab initio calculations and vibrationally resolved photoelectron imaging investigation".JOURNAL OF CHEMICAL PHYSICS 139.9(2013).
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Liu, Zhiling]的文章
[Qin, Zhengbo]的文章
[Xie, Hua]的文章
百度学术
百度学术中相似的文章
[Liu, Zhiling]的文章
[Qin, Zhengbo]的文章
[Xie, Hua]的文章
必应学术
必应学术中相似的文章
[Liu, Zhiling]的文章
[Qin, Zhengbo]的文章
[Xie, Hua]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。