DICP OpenIR
Asymmetric hydrogenolysis of racemic tertiary alcohols, 3-substituted 3-hydroxyisoindolin-1-ones
Chen, Mu-Wang; Chen, Qing-An; Duan, Ying; Ye, Zhi-Shi; Zhou, Yong-Gui
Source PublicationCHEMICAL COMMUNICATIONS
2012
DOI10.1039/c2cc16832d
Volume48Issue:11Pages:1698-1700
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordORGANOCATALYTIC TRANSFER HYDROGENATION ; HIGHLY DIASTEREOSELECTIVE SYNTHESIS ; CATALYZED TRANSFER HYDROGENATION ; REDUCTIVE AMINATION ; HANTZSCH ESTERS ; ISOINDOLIN-1-ONE DERIVATIVES ; ENANTIOSELECTIVE REDUCTION ; CARBON STEREOCENTERS ; IONIC HYDROGENATION ; SODIUM-BOROHYDRIDE
AbstractAsymmetric hydrogenolysis of racemic tertiary alcohols, 3-substituted 3-hydroxyisoindolin-1-ones, was developed using chiral phosphoric acid as catalyst and a Hantzsch ester as the hydrogen source with up to 95% ee. The reaction process of this asymmetric transfer hydrogenation may occur directly through the acyliminium ion intermediate.
Language英语
WOS IDWOS:000299053400023
Citation statistics
Cited Times:58[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138020
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Chen, Mu-Wang,Chen, Qing-An,Duan, Ying,et al. Asymmetric hydrogenolysis of racemic tertiary alcohols, 3-substituted 3-hydroxyisoindolin-1-ones[J]. CHEMICAL COMMUNICATIONS,2012,48(11):1698-1700.
APA Chen, Mu-Wang,Chen, Qing-An,Duan, Ying,Ye, Zhi-Shi,&Zhou, Yong-Gui.(2012).Asymmetric hydrogenolysis of racemic tertiary alcohols, 3-substituted 3-hydroxyisoindolin-1-ones.CHEMICAL COMMUNICATIONS,48(11),1698-1700.
MLA Chen, Mu-Wang,et al."Asymmetric hydrogenolysis of racemic tertiary alcohols, 3-substituted 3-hydroxyisoindolin-1-ones".CHEMICAL COMMUNICATIONS 48.11(2012):1698-1700.
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