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Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr
Yang, Gang1,2; Wang, Lianyue1,3; Li, Jun1; Zhang, Yi1; Dong, Xiaoli2; Lv, Ying1; Gao, Shuang1
关键词Oxidation Alcohol Nhpi Copper Oxygen
刊名RESEARCH ON CHEMICAL INTERMEDIATES
2012-03-01
DOI10.1007/s11164-011-0416-6
38期:3-5页:775-783
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]VANADIUM COCATALYSTS ; CARBONYL-COMPOUNDS ; MILD CONDITIONS ; ATOM ECONOMY ; DIOXYGEN ; PHTHALIMIDE ; CATALYSIS ; OXYGEN
英文摘要A new catalytic system for oxidation of alcohols with oxygen by N-hydroxyphthalimide (NHPI) combined with CuBr has been developed. The reaction results showed that this catalytic system can effectively catalyze the oxidation of alcohols to the corresponding carboxylic acids or ketones. We obtained 100% selectivity for acetophenone at 94.2% conversion of phenylethanol at 75 degrees C for 20 h. A mechanism of oxidation of alcohols catalyzed by NHPI/CuBr was proposed.
语种英语
WOS记录号WOS:000302146500008
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138023
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Polytech Univ, Sch Chem & Mat, Dalian 116034, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Yang, Gang,Wang, Lianyue,Li, Jun,et al. Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2012,38(3-5):775-783.
APA Yang, Gang.,Wang, Lianyue.,Li, Jun.,Zhang, Yi.,Dong, Xiaoli.,...&Gao, Shuang.(2012).Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr.RESEARCH ON CHEMICAL INTERMEDIATES,38(3-5),775-783.
MLA Yang, Gang,et al."Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr".RESEARCH ON CHEMICAL INTERMEDIATES 38.3-5(2012):775-783.
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