中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Calcium amidoborane, a new reagent for chemoselective reduction of alpha,beta-unsaturated aldehydes and ketones to allylic alcohols
作者: Xu, Weiliang1;  Wang, Ruimin2;  Wu, Guotao2;  Chen, Ping2
刊名: RSC ADVANCES
发表日期: 2012
DOI: 10.1039/c2ra01291j
卷: 2, 期:14, 页:6005-6010
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Calcium amidoborane (Ca(NH2BH3)(2), CaAB) is a new member of the borohydride family, which possesses interesting dehydrogenation features. CaAB also exhibits superior performance in chemoselective reduction. Our experimental results show that CaAB can reduce alpha,beta-unsaturated carbonyl compounds chemoselectively to the corresponding allylic alcohols at ambient temperature.
关键词[WOS]: HYDROGEN-STORAGE MATERIALS ;  AMMONIA-BORANE ;  SODIUM-BOROHYDRIDE ;  SELECTIVE REDUCTION ;  CARBONYL-COMPOUNDS ;  CONJUGATED KETONES ;  CRYSTAL-STRUCTURES ;  LITHIUM ;  AMINATION ;  NABH4
语种: 英语
WOS记录号: WOS:000305693700020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138038
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Natl Univ Singapore, Singapore 117548, Singapore
2.Dalian Inst Chem Phys, Dalian, Peoples R China

Recommended Citation:
Xu, Weiliang,Wang, Ruimin,Wu, Guotao,et al. Calcium amidoborane, a new reagent for chemoselective reduction of alpha,beta-unsaturated aldehydes and ketones to allylic alcohols[J]. RSC ADVANCES,2012,2(14):6005-6010.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xu, Weiliang]'s Articles
 [Wang, Ruimin]'s Articles
 [Wu, Guotao]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xu, Weiliang]‘s Articles
 [Wang, Ruimin]‘s Articles
 [Wu, Guotao]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace