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Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization
Shiung, Kui Shiu1,2; Yu, Dan1,3; Tzeng, Sheng Yuan1,2; Tzeng, Wen Bih1,2
刊名CHEMICAL PHYSICS LETTERS
2012-02-06
DOI10.1016/j.cplett.2011.12.055
524页:38-41
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]SINGLET PI>>-PI STATES ; AB-INITIO CALCULATIONS ; INFRARED-SPECTROSCOPY ; DIPOLE MOMENTS ; GAS-PHASE ; FLUOROPHENOL ; 2-FLUOROANISOLE ; ROTAMERS ; 4-FLUOROANISOLE ; METHOXYPHENOL
英文摘要We applied the two-color resonant two-photon mass-analyzed threshold ionization spectroscopic technique to record the cation spectra of o-fluoroanisole and p-fluoroanisole. The adiabatic ionization energies of these two structural isomers were found to be 67354 +/- 5 and 66437 +/- 5 cm(-1), respectively. The observed active normal modes of the cations mainly result from the in-plane ring and substituent-sensitive vibrations. The results suggest that the relative location of the F and OCH3 substituents can slightly influence the transition energy and molecular vibrations. (C) 2012 Elsevier B. V. All rights reserved.
语种英语
WOS记录号WOS:000299317600007
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138044
专题中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan
3.Chinese Acad Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
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Shiung, Kui Shiu,Yu, Dan,Tzeng, Sheng Yuan,et al. Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization[J]. CHEMICAL PHYSICS LETTERS,2012,524:38-41.
APA Shiung, Kui Shiu,Yu, Dan,Tzeng, Sheng Yuan,&Tzeng, Wen Bih.(2012).Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization.CHEMICAL PHYSICS LETTERS,524,38-41.
MLA Shiung, Kui Shiu,et al."Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization".CHEMICAL PHYSICS LETTERS 524(2012):38-41.
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