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Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines
He Wei; He Songbo; Sun Chenglin; Wu Kaikai; Wang Liandi; Yu Zhengkun
关键词Platinum Tin Alumina Supported Catalyst Borrowing Hydrogen Heterogeneous Catalysis N-alkylation Amine Alcohol
刊名CHINESE JOURNAL OF CATALYSIS
2012-04-01
DOI10.3724/SP.J.1088.2012.11105
33期:4页:717-722
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]ASTERISK-IR COMPLEX ; BORROWING HYDROGEN ; ORGANIC-SYNTHESIS ; ALCOHOLS ; SULFONAMIDES ; HETEROCYCLIZATION ; DEHYDROGENATION ; ACTIVATION ; AMINATION ; VERSATILE
英文摘要N-Alkylation of amines with alcohols through a borrowing hydrogen strategy is a green route to amines. Heterogeneous bimetallic Pt-Sn/gamma-Al2O3 catalyzed the reactions of primary (secondary) amines with alcohols in the absence of external hydrogen source, efficiently affording secondary (tertiary) amines with water and a small amount of imines as the by-products. Various functional groups in the substrates were tolerated in the catalytic system. The Pt-Sn/gamma-Al2O3 catalyst was easily recycled, suggesting its potential application in the production of secondary and tertiary amines.
语种英语
WOS记录号WOS:000303360300020
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被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138057
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
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GB/T 7714
He Wei,He Songbo,Sun Chenglin,et al. Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines[J]. CHINESE JOURNAL OF CATALYSIS,2012,33(4):717-722.
APA He Wei,He Songbo,Sun Chenglin,Wu Kaikai,Wang Liandi,&Yu Zhengkun.(2012).Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines.CHINESE JOURNAL OF CATALYSIS,33(4),717-722.
MLA He Wei,et al."Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines".CHINESE JOURNAL OF CATALYSIS 33.4(2012):717-722.
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