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题名: C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation
作者: Song, Guoyong1;  Wang, Fen1;  Li, Xingwei1
刊名: CHEMICAL SOCIETY REVIEWS
发表日期: 2012
DOI: 10.1039/c2cs15281a
卷: 41, 期:9, 页:3651-3678
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Rhodium(III)-catalyzed direct functionalization of C-H bonds under oxidative conditions leading to C-C, C-N, and C-O bond formation is reviewed. Various arene substrates bearing nitrogen and oxygen directing groups are covered in their coupling with unsaturated partners such as alkenes and alkynes. The facile construction of C-E (E = C, N, S, or O) bonds makes Rh(III) catalysis an attractive step-economic approach to value-added molecules from readily available starting materials. Comparisons and contrasts between rhodium(III) and palladium(II)-catalyzed oxidative coupling are made. The remarkable diversity of structures accessible is demonstrated with various recent examples, with a proposed mechanism for each transformation being briefly summarized (critical review, 138 references).
关键词[WOS]: INTRAMOLECULAR ALKANE ARYLATION ;  INTERNAL ALKYNES ;  BENZOIC-ACIDS ;  COUPLING REACTIONS ;  ROOM-TEMPERATURE ;  RHODIUM CATALYSIS ;  BORONIC ACIDS ;  DERIVATIVES ;  CLEAVAGE ;  RH
语种: 英语
WOS记录号: WOS:000302559700014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138081
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Song, Guoyong,Wang, Fen,Li, Xingwei. C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation[J]. CHEMICAL SOCIETY REVIEWS,2012,41(9):3651-3678.
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