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C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation
Song, Guoyong; Wang, Fen; Li, Xingwei
Source PublicationCHEMICAL SOCIETY REVIEWS
2012
DOI10.1039/c2cs15281a
Volume41Issue:9Pages:3651-3678
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordINTRAMOLECULAR ALKANE ARYLATION ; INTERNAL ALKYNES ; BENZOIC-ACIDS ; COUPLING REACTIONS ; ROOM-TEMPERATURE ; RHODIUM CATALYSIS ; BORONIC ACIDS ; DERIVATIVES ; CLEAVAGE ; RH
AbstractRhodium(III)-catalyzed direct functionalization of C-H bonds under oxidative conditions leading to C-C, C-N, and C-O bond formation is reviewed. Various arene substrates bearing nitrogen and oxygen directing groups are covered in their coupling with unsaturated partners such as alkenes and alkynes. The facile construction of C-E (E = C, N, S, or O) bonds makes Rh(III) catalysis an attractive step-economic approach to value-added molecules from readily available starting materials. Comparisons and contrasts between rhodium(III) and palladium(II)-catalyzed oxidative coupling are made. The remarkable diversity of structures accessible is demonstrated with various recent examples, with a proposed mechanism for each transformation being briefly summarized (critical review, 138 references).
Language英语
WOS IDWOS:000302559700014
Citation statistics
Cited Times:1507[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138081
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Song, Guoyong,Wang, Fen,Li, Xingwei. C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation[J]. CHEMICAL SOCIETY REVIEWS,2012,41(9):3651-3678.
APA Song, Guoyong,Wang, Fen,&Li, Xingwei.(2012).C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation.CHEMICAL SOCIETY REVIEWS,41(9),3651-3678.
MLA Song, Guoyong,et al."C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation".CHEMICAL SOCIETY REVIEWS 41.9(2012):3651-3678.
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