DICP OpenIR
Remarkable dependence of electrochemical performance of SrCo0.8Fe0.2O3-delta on A-site nonstoichiometry
Liu, Huanying1,2; Zhu, Xuefeng1; Cong, You1; Zhang, Tianyu1; Yang, Weishen1
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
2012
DOI10.1039/c2cp41060e
Volume14Issue:20Pages:7234-7239
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordOXIDE FUEL-CELLS ; INTERMEDIATE TEMPERATURE SOFCS ; ANODE MATERIALS ; COMPOSITE CATHODES ; OXYGEN PERMEATION ; ELECTRICAL-CONDUCTIVITY ; POWER-DENSITY ; IT-SOFC ; PEROVSKITES ; ELECTROLYTE
AbstractSrCo0.8Fe0.2O3-delta is a controversial material whether it is used as an oxygen permeable membrane or as a cathode of solid oxide fuel cells. In this paper, carefully synthesized powders of perovskite-type SrxCo0.8Fe0.2O3-delta (x = 0.80-1.20) oxides are utilized to investigate the effect of A-site nonstoichiometry on their electrochemical performance. The electrical conductivity, sintering property and stability in ambient air of SrxCo0.8Fe0.2O3-delta are critically dependent on the A-site nonstoichiometry. Sr1.00Co0.8Fe0.2O3-delta has a single-phase cubic perovskite structure, but a cobalt-iron oxide impurity appears in A-site cation deficient samples and Sr-3(Co, Fe)(2)O7-delta appears when there is an A-site cation excess. It was found that the presence of the cobalt-iron oxide improves the electrochemical performance. However, Sr-3(Co, Fe)(2)O7-delta has a significant negative influence on the electrochemical activity for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The peak power densities with a single-layer Sr1.00Co0.8Fe0.2O3-delta cathode are 275, 475, 749 and 962 mW cm(-2) at 550, 600, 650 and 700 degrees C, respectively, values which are slightly lower than those for Sr0.95Co0.8Fe0.2O3-delta (e.g. 1025 mW cm(-2) at 700 degrees C) but much higher than those for Sr1.05Co0.8Fe0.2O3-delta (e.g. only 371 mW cm(-2) at 700 degrees C). This remarkable dependence of electrochemical performance of the SrxCo0.8Fe0.2O3-delta cathode on the A-site nonstoichiometry reveals that lower values of electrochemical activity reported in the literature may be induced by an A-site cation excess. Therefore, to obtain a high performance of SrxCo0.8Fe0.2O3-delta cathode for IT-SOFCs, an A-site cation excess must be avoided.
Language英语
WOS IDWOS:000303444000006
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138096
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Liu, Huanying,Zhu, Xuefeng,Cong, You,et al. Remarkable dependence of electrochemical performance of SrCo0.8Fe0.2O3-delta on A-site nonstoichiometry[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2012,14(20):7234-7239.
APA Liu, Huanying,Zhu, Xuefeng,Cong, You,Zhang, Tianyu,&Yang, Weishen.(2012).Remarkable dependence of electrochemical performance of SrCo0.8Fe0.2O3-delta on A-site nonstoichiometry.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,14(20),7234-7239.
MLA Liu, Huanying,et al."Remarkable dependence of electrochemical performance of SrCo0.8Fe0.2O3-delta on A-site nonstoichiometry".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 14.20(2012):7234-7239.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Huanying]'s Articles
[Zhu, Xuefeng]'s Articles
[Cong, You]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Huanying]'s Articles
[Zhu, Xuefeng]'s Articles
[Cong, You]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Huanying]'s Articles
[Zhu, Xuefeng]'s Articles
[Cong, You]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.