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题名: Biomimetic in situ Regeneration of Cofactors NAD(P)(+) and NAD(P)H Models Hantzsch Esters and Dihydrophenanthridine
作者: Du, Wangming1;  Yu, Zhengkun1
关键词: biomimetic ;  regeneration ;  asymmetric hydrogenation ;  Hantzsch esters ;  dihydrophenanthridine
刊名: SYNLETT
发表日期: 2012-06-01
DOI: 10.1055/s-0031-1291005
期: 9, 页:1300-1304
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Biomimetic recycling of the expensive cofactors NAD(P)H/NAD(P)(+) and their models is a promising area in bio-inspired synthesis. This paper highlights the recent advances in the in situ regeneration of the oxidized cofactors NAD(P)(+) through oxidation of cofactors NAD(P)H in the presence of an alcohol dehydrogenase by means of dioxygen and a synthetic Fe(III) porphyrin as a biomimetic NAD(P)H oxidase or flavin as catalyst, and biomimetic in situ regeneration of the expensive NAD(P)H models Hantzsch esters (HEH) and 9,10-dihydrophenanthridine (DHPD) by transition-metal and chiral Bronsted acid catalyzed relay asymmetric hydrogenation.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  REDUCTION ;  EFFICIENT
语种: 英语
WOS记录号: WOS:000305014900005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138104
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Du, Wangming,Yu, Zhengkun. Biomimetic in situ Regeneration of Cofactors NAD(P)(+) and NAD(P)H Models Hantzsch Esters and Dihydrophenanthridine[J]. SYNLETT,2012(9):1300-1304.
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