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题名: Temperature-programmed desorption of CO and NO over gamma-Mo2N
作者: Yang, SW;  Li, YX;  Ji, CX;  Li, C;  Xin, Q
关键词: gamma-Mo2N ;  temperature-programmed desorption ;  CO ;  NO ;  chemisorption ;  coordinatively unsaturated sites ;  hydrogen
刊名: JOURNAL OF CATALYSIS
发表日期: 1998-02-15
卷: 174, 期:1, 页:34-42
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The temperature-programmed desorption-mass spectroscopy technique has been used to characterize the desorption behaviors of adsorbed CO and NO on gamma-Mo2N. It has been found that adsorbed CO is desorbed with a prominent peak at 383 K and a shoulder at 423 K, without evidence of any decomposition. This suggests that the aggressive adsorption of molybdenum toward CO has been modified considerably by nitridation to resemble the properties of the Group WI metals. After synthesis there is some NH3 left on the Mo2N sample, which decomposes upon heating and the hydrogen liberated helps reduce the sample to certain extents, according to the conditions employed. Reducing the sample with hydrogen at high temperatures can produce coordinatively unsaturated sites of Mo whose number and nature are important to the interaction between the sample and CO and NO. Three types of active sites on the reduced Mo2N to adsorb NO with low, medium, and high adsorption energies have been found, from which NO is desorbed at 393, 503, and 543 K, respectively. In addition to NO, N-2 and N2O were detected as desorption products, which suggests that adsorbed NO undergoes decomposition and disproportionation reactions under appropriate conditions. The results of NO adsorbed on H-2-preadsorbed Mo2N show that the adsorption and reaction of NO on the sample is very much affected by preadsorbed hydrogen dosed at 673 K. The reactions between the reversely migrated hydrogen and the other surface species have also been discussed. (C) 1998 Academic Press.
关键词[WOS]: TRANSITION-METAL CARBIDES ;  MOLYBDENUM NITRIDE CATALYSTS ;  SURFACE-AREA ;  NMR-SPECTROSCOPY ;  NH3 ;  HYDRODENITROGENATION ;  MO(100) ;  OXIDE ;  MO2N ;  DECOMPOSITION
语种: 英语
WOS记录号: WOS:000072344700004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138127
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Liverpool, Leverhulme Ctr Innovat Catalysis, Liverpool L69 3BX, Merseyside, England
3.Univ Liverpool, IRC, Liverpool L69 3BX, Merseyside, England

Recommended Citation:
Yang, SW,Li, YX,Ji, CX,et al. Temperature-programmed desorption of CO and NO over gamma-Mo2N[J]. JOURNAL OF CATALYSIS,1998,174(1):34-42.
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