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题名: Investigation of the mass transport of electroactive compounds in an SPE membrane used for electro-organic synthesis
作者: Jiang, JH;  Wu, BL;  Cha, CS
关键词: solid polymer electrolyte ;  Nafion (R) membrane ;  electroactive compounds ;  mass transport ;  electro-organic synthesis
刊名: JOURNAL OF ELECTROANALYTICAL CHEMISTRY
发表日期: 1998-04-15
卷: 446, 期:1-2, 页:159-163
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Electrochemistry
研究领域[WOS]: Chemistry ;  Electrochemistry
英文摘要: The mass transport of electroactive compounds in a commercial SPE membrane was investigated using SPE composite microelectrodes. The diffusion coefficient and concentration of electroactive compounds in the membrane were measured by chronoamperometry and voltammetry. The experimental results indicate that electroactive compounds in the membrane diffuse as in a fluid electrolyte solution, except more slowly, but faster than in a recast SPE membrane; and the concentration of electroactive compounds dissolved in the membrane differs from that in bulk solution. (C) 1998 Elsevier Science S.A. All rights reserved.
关键词[WOS]: ION-EXCHANGE MEMBRANES ;  SOLID-STATE VOLTAMMETRY ;  POLYMER ELECTROLYTE ;  NAFION FILMS ;  DIFFUSION ;  ELECTROCHEMISTRY
语种: 英语
WOS记录号: WOS:000073907500017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138136
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalyst, Dalian 116023, Peoples R China

Recommended Citation:
Jiang, JH,Wu, BL,Cha, CS. Investigation of the mass transport of electroactive compounds in an SPE membrane used for electro-organic synthesis[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,1998,446(1-2):159-163.
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