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题名: Photodissociation of chlorobenzene at 266 nm
作者: Wang, GJ;  Zhu, RS;  Zhang, H;  Han, KL;  He, GZ;  Lou, NQ
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 1998-05-22
卷: 288, 期:2-4, 页:429-432
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The photodissociation of C6H5Cl at 266 nm has been investigated using the crossed laser-molecular beam technique. The translational energy distribution of the Cl photofragment is obtained. The TOF spectrum of the Cl fragment consists of only one component. Ab initio calculation shows that the first excited state of chlorobenzene has large geometry changes compared to that of the ground state. The hot molecule mechanism is considered to be probable for the dissociation of C6H5Cl at 266 nm. (C) 1998 Elsevier Science B.V. All rights reserved.
关键词[WOS]: EXCITED-STATES ;  193 NM ;  FRAGMENT
语种: 英语
WOS记录号: WOS:000074007900042
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138156
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Wang, GJ,Zhu, RS,Zhang, H,et al. Photodissociation of chlorobenzene at 266 nm[J]. CHEMICAL PHYSICS LETTERS,1998,288(2-4):429-432.
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