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Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde
Zhang, YK; Liao, SJ; Xu, Y; Yu, DR; Ju, SY; Guan, ZX
关键词Selective Hydrogenation Bimetallic Catalysts 3-phenylpropanal Cinnamaldehyde
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
1998-11-01
19期:11页:1823-1825
收录类别SCI
文章类型Letter
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]COLLOIDS ; REDUCTION
英文摘要The bimetallic catalysts, PdCl2-0.5MY-PPh3 [MY = NiCl2, Ni(OAc)(2), Fe(acac)(3), Co(OAc)(2), Co(acac)(2) or CoCl2] reduced by NaBH4, exhibit much higher selectivity in comparison with that of the monometallic Pa catalyst in the selective hydrogenation of cinnamaldehyde to 3-phenylpropanal at 66 degrees C under atmospheric pressure, A strong synergic effect occurs between Pd and the second metal component for the high selectivity. Among these catalysts, PdCl2-0.5Co(OAc)(2)-PPh3 reduced by NaBH4 is the best catalyst.
语种英语
WOS记录号WOS:000078261700032
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138158
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Railway Inst, Dept Appl Chem, Dalian 116028, Peoples R China
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GB/T 7714
Zhang, YK,Liao, SJ,Xu, Y,et al. Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1998,19(11):1823-1825.
APA Zhang, YK,Liao, SJ,Xu, Y,Yu, DR,Ju, SY,&Guan, ZX.(1998).Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,19(11),1823-1825.
MLA Zhang, YK,et al."Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 19.11(1998):1823-1825.
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