DICP OpenIR
Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde
Zhang, YK; Liao, SJ; Xu, Y; Yu, DR; Ju, SY; Guan, ZX
KeywordSelective Hydrogenation Bimetallic Catalysts 3-phenylpropanal Cinnamaldehyde
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
1998-11-01
Volume19Issue:11Pages:1823-1825
Indexed BySCI
SubtypeLetter
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCOLLOIDS ; REDUCTION
AbstractThe bimetallic catalysts, PdCl2-0.5MY-PPh3 [MY = NiCl2, Ni(OAc)(2), Fe(acac)(3), Co(OAc)(2), Co(acac)(2) or CoCl2] reduced by NaBH4, exhibit much higher selectivity in comparison with that of the monometallic Pa catalyst in the selective hydrogenation of cinnamaldehyde to 3-phenylpropanal at 66 degrees C under atmospheric pressure, A strong synergic effect occurs between Pd and the second metal component for the high selectivity. Among these catalysts, PdCl2-0.5Co(OAc)(2)-PPh3 reduced by NaBH4 is the best catalyst.
Language英语
WOS IDWOS:000078261700032
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138158
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Railway Inst, Dept Appl Chem, Dalian 116028, Peoples R China
Recommended Citation
GB/T 7714
Zhang, YK,Liao, SJ,Xu, Y,et al. Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1998,19(11):1823-1825.
APA Zhang, YK,Liao, SJ,Xu, Y,Yu, DR,Ju, SY,&Guan, ZX.(1998).Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,19(11),1823-1825.
MLA Zhang, YK,et al."Bimetallic synergic effect in the selective catalytic hydrogenation of cinnamaldehyde".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 19.11(1998):1823-1825.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, YK]'s Articles
[Liao, SJ]'s Articles
[Xu, Y]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, YK]'s Articles
[Liao, SJ]'s Articles
[Xu, Y]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, YK]'s Articles
[Liao, SJ]'s Articles
[Xu, Y]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.