中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Mono- and bimetallic catalytic hollow-fiber reactors for the selective hydrogenation of butadiene in 1-butene
作者: Liu, CQ;  Xu, Y;  Liao, SJ;  Yu, DR
关键词: catalytic hollow-fiber reactor ;  polymer anchored mono- and bimetallic catalysts ;  synergic effect ;  selective hydrogenation ;  crude 1-butene
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 1998-08-24
卷: 172, 期:1, 页:23-29
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: The monometallic catalytic membrane reactors were established with catalytic hollow fibers prepared by supporting the polymer-anchored monometallic palladium catalyst (PVP-Pd, EC-Pd or AR-Pd) on the inside wall of CA or PSF hollow fibers. PVP=poly(N-vinyl-2-pyrrolidone), EC=ethyl cellulose, AR=melamine-formaldehyde resin, CA=Cellulose acetate, PSF=polysulfone. The selective hydrogenation of butadiene in crude 1-butene was carried out in the catalytic membrane reactors at 40 degrees C under 0.1 MPa. Among the above catalytic hollow fibers, the catalytic activity and selectivity of the PVP-Pd/ CA monometallic hollow fiber were the best values, but there was still 2.6% 2-butene in the product. In order to inhibit the isomerization reaction of 1-butene, the bimetallic catalytic CA hollow-fiber reactors were produced and used for the above reaction. The bimetallic palladium-cobalt catalyst PVP-PdCl2-0.5Co(OAc)(2), supported on the CA hollow fibers was reduced by NH2NH2 or NaBH4. A remarkable synergic effect of palladium and cobalt reduced by NaBH4 was observed. (C) 1998 Elsevier Science B.V. All rights reserved.
关键词[WOS]: HOMOGENEOUS MULTIMETALLIC CATALYSTS ;  MEMBRANE REACTOR ;  PALLADIUM-RUTHENIUM ;  NITROAROMATICS ;  PERVAPORATION ;  IODIDES
语种: 英语
WOS记录号: WOS:000076042800004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138162
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Liu, CQ,Xu, Y,Liao, SJ,et al. Mono- and bimetallic catalytic hollow-fiber reactors for the selective hydrogenation of butadiene in 1-butene[J]. APPLIED CATALYSIS A-GENERAL,1998,172(1):23-29.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Liu, CQ]'s Articles
 [Xu, Y]'s Articles
 [Liao, SJ]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Liu, CQ]‘s Articles
 [Xu, Y]‘s Articles
 [Liao, SJ]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace