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题名: Rotational alignment of products from NOCl+Sr chemiluminescent reaction
作者: Zhan, JP;  Yang, HP;  Han, KL;  Wang, ML;  Deng, WQ;  He, GZ;  Lou, NQ
刊名: JOURNAL OF CHEMICAL PHYSICS
发表日期: 1998-08-01
卷: 109, 期:5, 页:1819-1823
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: The chemiluminescent reactions Sr + NOCl-->SrCl(A,B) + NO are studied under the single collision conditions in a beam-gas arrangement. The product rotational alignment [P-2( (J) over cap'.(k) over cap)] = -0.40 +/-0.05 for SrCl(B) is obtained from Sr+NOCl chemiluminescent reactions. In addition, the electronic state branching ratio and the product vibrational state distribution have been roughly estimated by simulating the chemiluminescent spectra of SrCl. Quasiclassical trajectory (QCT) calculations for the Sr+NOCl reaction as a three-body system have been carried out. The calculated results agree;well with the experimental ones. (C) 1998 American Institute of Physics.
关键词[WOS]: LASER-INDUCED FLUORESCENCE ;  SPIN-ORBIT STATE ;  ANGULAR-MOMENTUM ;  HALOGENATED METHANES ;  EXCHANGE-REACTIONS ;  REACTION DYNAMICS ;  ALKYL BROMIDES ;  POLARIZATION ;  DEPENDENCE ;  VELOCITY
语种: 英语
WOS记录号: WOS:000075066300030
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138180
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Zhan, JP,Yang, HP,Han, KL,et al. Rotational alignment of products from NOCl+Sr chemiluminescent reaction[J]. JOURNAL OF CHEMICAL PHYSICS,1998,109(5):1819-1823.
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