DICP OpenIR
Rotational alignment of products from NOCl+Sr chemiluminescent reaction
Zhan, JP; Yang, HP; Han, KL; Wang, ML; Deng, WQ; He, GZ; Lou, NQ
Source PublicationJOURNAL OF CHEMICAL PHYSICS
1998-08-01
Volume109Issue:5Pages:1819-1823
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordLASER-INDUCED FLUORESCENCE ; SPIN-ORBIT STATE ; ANGULAR-MOMENTUM ; HALOGENATED METHANES ; EXCHANGE-REACTIONS ; REACTION DYNAMICS ; ALKYL BROMIDES ; POLARIZATION ; DEPENDENCE ; VELOCITY
AbstractThe chemiluminescent reactions Sr + NOCl-->SrCl(A,B) + NO are studied under the single collision conditions in a beam-gas arrangement. The product rotational alignment [P-2( (J) over cap'.(k) over cap)] = -0.40 +/-0.05 for SrCl(B) is obtained from Sr+NOCl chemiluminescent reactions. In addition, the electronic state branching ratio and the product vibrational state distribution have been roughly estimated by simulating the chemiluminescent spectra of SrCl. Quasiclassical trajectory (QCT) calculations for the Sr+NOCl reaction as a three-body system have been carried out. The calculated results agree;well with the experimental ones. (C) 1998 American Institute of Physics.
Language英语
WOS IDWOS:000075066300030
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138180
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhan, JP,Yang, HP,Han, KL,et al. Rotational alignment of products from NOCl+Sr chemiluminescent reaction[J]. JOURNAL OF CHEMICAL PHYSICS,1998,109(5):1819-1823.
APA Zhan, JP.,Yang, HP.,Han, KL.,Wang, ML.,Deng, WQ.,...&Lou, NQ.(1998).Rotational alignment of products from NOCl+Sr chemiluminescent reaction.JOURNAL OF CHEMICAL PHYSICS,109(5),1819-1823.
MLA Zhan, JP,et al."Rotational alignment of products from NOCl+Sr chemiluminescent reaction".JOURNAL OF CHEMICAL PHYSICS 109.5(1998):1819-1823.
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