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Rotational alignment of products from NOCl+Sr chemiluminescent reaction
Zhan, JP; Yang, HP; Han, KL; Wang, ML; Deng, WQ; He, GZ; Lou, NQ
刊名JOURNAL OF CHEMICAL PHYSICS
1998-08-01
109期:5页:1819-1823
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]LASER-INDUCED FLUORESCENCE ; SPIN-ORBIT STATE ; ANGULAR-MOMENTUM ; HALOGENATED METHANES ; EXCHANGE-REACTIONS ; REACTION DYNAMICS ; ALKYL BROMIDES ; POLARIZATION ; DEPENDENCE ; VELOCITY
英文摘要The chemiluminescent reactions Sr + NOCl-->SrCl(A,B) + NO are studied under the single collision conditions in a beam-gas arrangement. The product rotational alignment [P-2( (J) over cap'.(k) over cap)] = -0.40 +/-0.05 for SrCl(B) is obtained from Sr+NOCl chemiluminescent reactions. In addition, the electronic state branching ratio and the product vibrational state distribution have been roughly estimated by simulating the chemiluminescent spectra of SrCl. Quasiclassical trajectory (QCT) calculations for the Sr+NOCl reaction as a three-body system have been carried out. The calculated results agree;well with the experimental ones. (C) 1998 American Institute of Physics.
语种英语
WOS记录号WOS:000075066300030
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138180
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Zhan, JP,Yang, HP,Han, KL,et al. Rotational alignment of products from NOCl+Sr chemiluminescent reaction[J]. JOURNAL OF CHEMICAL PHYSICS,1998,109(5):1819-1823.
APA Zhan, JP.,Yang, HP.,Han, KL.,Wang, ML.,Deng, WQ.,...&Lou, NQ.(1998).Rotational alignment of products from NOCl+Sr chemiluminescent reaction.JOURNAL OF CHEMICAL PHYSICS,109(5),1819-1823.
MLA Zhan, JP,et al."Rotational alignment of products from NOCl+Sr chemiluminescent reaction".JOURNAL OF CHEMICAL PHYSICS 109.5(1998):1819-1823.
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