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Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides
Guerrero-Ruiz, A; Zhang, Y; Bachiller-Baeza, B; Rodriguez-Ramos, I
KeywordMolybdenum Nitride Catalysts Crotonaldehyde Hydrogenation
Source PublicationCATALYSIS LETTERS
1998
Volume55Issue:3-4Pages:165-168
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordALPHA,BETA-UNSATURATED ALDEHYDES ; CATALYSTS ; SELECTIVITY ; CINNAMALDEHYDE ; PLATINUM ; CARBIDES
AbstractThe gas-phase hydrogenation of crotonaldehyde has been performed over unsupported Mo(2)N and over Mo(2)N supported on two carbonaceous materials, an activated carbon (AC) and a high surface area graphite (G). These catalysts were in situ prepared by the temperature-programmed reaction of MoO(3) and carbon-supported Mo precursors with NH(3). It is found that selectivity to the unsaturated alcohol is maximum for the Mo(2)N/G sample, where crotylalcohol selectivities exceed the 60% during all time in reaction. Higher selectivity surface sites are associated with the (200) planes of the gamma-Mo(2)N crystallites.
Language英语
WOS IDWOS:000077537200006
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138191
Collection中国科学院大连化学物理研究所
Affiliation1.Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan, Madrid 28040, Spain
2.CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,et al. Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides[J]. CATALYSIS LETTERS,1998,55(3-4):165-168.
APA Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,&Rodriguez-Ramos, I.(1998).Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides.CATALYSIS LETTERS,55(3-4),165-168.
MLA Guerrero-Ruiz, A,et al."Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides".CATALYSIS LETTERS 55.3-4(1998):165-168.
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