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题名: Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides
作者: Guerrero-Ruiz, A;  Zhang, Y;  Bachiller-Baeza, B;  Rodriguez-Ramos, I
关键词: molybdenum nitride catalysts ;  crotonaldehyde hydrogenation
刊名: CATALYSIS LETTERS
发表日期: 1998
卷: 55, 期:3-4, 页:165-168
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The gas-phase hydrogenation of crotonaldehyde has been performed over unsupported Mo(2)N and over Mo(2)N supported on two carbonaceous materials, an activated carbon (AC) and a high surface area graphite (G). These catalysts were in situ prepared by the temperature-programmed reaction of MoO(3) and carbon-supported Mo precursors with NH(3). It is found that selectivity to the unsaturated alcohol is maximum for the Mo(2)N/G sample, where crotylalcohol selectivities exceed the 60% during all time in reaction. Higher selectivity surface sites are associated with the (200) planes of the gamma-Mo(2)N crystallites.
关键词[WOS]: ALPHA,BETA-UNSATURATED ALDEHYDES ;  CATALYSTS ;  SELECTIVITY ;  CINNAMALDEHYDE ;  PLATINUM ;  CARBIDES
语种: 英语
WOS记录号: WOS:000077537200006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138191
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan, Madrid 28040, Spain
2.CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,et al. Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides[J]. CATALYSIS LETTERS,1998,55(3-4):165-168.
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