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Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides
Guerrero-Ruiz, A; Zhang, Y; Bachiller-Baeza, B; Rodriguez-Ramos, I
关键词Molybdenum Nitride Catalysts Crotonaldehyde Hydrogenation
刊名CATALYSIS LETTERS
1998
55期:3-4页:165-168
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ALPHA,BETA-UNSATURATED ALDEHYDES ; CATALYSTS ; SELECTIVITY ; CINNAMALDEHYDE ; PLATINUM ; CARBIDES
英文摘要The gas-phase hydrogenation of crotonaldehyde has been performed over unsupported Mo(2)N and over Mo(2)N supported on two carbonaceous materials, an activated carbon (AC) and a high surface area graphite (G). These catalysts were in situ prepared by the temperature-programmed reaction of MoO(3) and carbon-supported Mo precursors with NH(3). It is found that selectivity to the unsaturated alcohol is maximum for the Mo(2)N/G sample, where crotylalcohol selectivities exceed the 60% during all time in reaction. Higher selectivity surface sites are associated with the (200) planes of the gamma-Mo(2)N crystallites.
语种英语
WOS记录号WOS:000077537200006
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被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138191
专题中国科学院大连化学物理研究所
作者单位1.Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan, Madrid 28040, Spain
2.CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,et al. Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides[J]. CATALYSIS LETTERS,1998,55(3-4):165-168.
APA Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,&Rodriguez-Ramos, I.(1998).Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides.CATALYSIS LETTERS,55(3-4),165-168.
MLA Guerrero-Ruiz, A,et al."Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides".CATALYSIS LETTERS 55.3-4(1998):165-168.
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