中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride
作者: Jiang, H;  Xu, Y;  Liao, SJ;  Yu, DR;  Chen, H;  Li, XJ
关键词: carbonylation ;  allyl chloride ;  homogeneous bimetallic catalysts
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 1998-03-12
卷: 130, 期:1-2, 页:79-84
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: PdCl2(TPPTS)(2) [TPPTS = (m-C6H4SO3Na)(3)P] is used as catalyst in the carbonylation of allyl chloride. This catalyst exhibits very high activity and selectivity in the dilute alcoholic-aqueous NaOH/toluene medium under atmospheric pressure of carbon monoxide at 40 degrees C, Ethanol plays an important role for increasing the catalytic activity and selectivity of PdCl2(TPPTS)(2). The turnover reaches 2.7 x 10(4) (mol CO/mol Pd) in 21.5 h when the mole ratio of substrate/catalyst is 3 x 10(4). A synergic effect was observed when a second transition metal compound was added to the catalytic system. (C) 1998 Elsevier Science B.V.
关键词[WOS]: ATMOSPHERIC-PRESSURE CARBONYLATION ;  MULTIMETALLIC CATALYSTS ;  RUTHENIUM CATALYSTS ;  SODIUM-HYDROXIDE ;  COMPLEXES ;  HALIDES ;  HYDROFORMYLATION ;  HYDROGENATION ;  BEHAVIOR ;  IODIDES
语种: 英语
WOS记录号: WOS:000073456800008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138195
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China

Recommended Citation:
Jiang, H,Xu, Y,Liao, SJ,et al. Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1998,130(1-2):79-84.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Jiang, H]'s Articles
 [Xu, Y]'s Articles
 [Liao, SJ]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Jiang, H]‘s Articles
 [Xu, Y]‘s Articles
 [Liao, SJ]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace