DICP OpenIR
OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3
Wang, DZ; Li, ZL; Luo, CR; Weng, WZ; Wan, HL
KeywordKinetics Modelling Multiphase Reactions Selectivity Methane Oxidation Spillover
Source PublicationCHEMICAL ENGINEERING SCIENCE
2003-02-01
DOI10.1016/S0009-2509(02)00620-6
Volume58Issue:3-6Pages:887-893
Indexed ByISTP ; SCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
WOS SubjectEngineering, Chemical
WOS Research AreaEngineering
WOS KeywordSYNTHESIS GAS ; CATALYSTS ; TAP ; SYSTEM
AbstractThe microkinetics of the oxidation of methane on Ru/Al2O3 is developed using a TAP reactor. The shapes of the response curves of reactants and products are used to identify the elementary reactions and their rate parameters. The support, which strongly adsorbs H2O, participates in the reaction sequence through its supply of hydroxyl to metal particles by spillover, and this step is of kinetic significance. The relative rates of the elementary reactions that give overall partial oxidation or total oxidation are discussed. (C) 2003 Elsevier Science Ltd. All rights reserved.
Language英语
WOS IDWOS:000181575600045
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138216
Collection中国科学院大连化学物理研究所
Affiliation1.Tsing Hua Univ, Dept Chem Engn, Beijing 100084, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
Recommended Citation
GB/T 7714
Wang, DZ,Li, ZL,Luo, CR,et al. OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3[J]. CHEMICAL ENGINEERING SCIENCE,2003,58(3-6):887-893.
APA Wang, DZ,Li, ZL,Luo, CR,Weng, WZ,&Wan, HL.(2003).OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3.CHEMICAL ENGINEERING SCIENCE,58(3-6),887-893.
MLA Wang, DZ,et al."OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3".CHEMICAL ENGINEERING SCIENCE 58.3-6(2003):887-893.
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