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题名: Low-temperature heat capacity and thermodynamic properties of crystalline [RE(Gly)(3)(H2O)(2)]Cl-3 center dot 2H(2)O (RE = Pr, Nd, Gly = Glycine)
作者: Liu, BP;  Tan, ZC;  Lu, JL;  Lan, XZ;  Sun, LX;  Xu, F;  Yu, P;  Xing, J
关键词: [Pr(Gly)(3)(H2O)(2)]Cl-3 center dot 2H(2)O ;  [Nd(Gly)(3)(H2O)(2)]Cl-3 center dot 2H(2)O ;  heat capacity ;  TG analysis ;  rare-earth ;  glycine
刊名: THERMOCHIMICA ACTA
发表日期: 2003-02-21
卷: 397, 期:1-2, 页:67-73
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Heat capacities of two solid complexes of rare-earth elements with glycine [RE(Gly)(3)(H2O)(2)]Cl-3.2H(2)O (RE = Pr, Nd, Gly = Glycine) have been measured with a high-precision automatic adiabatic calorimeter over the temperature range from 78 to 380 K. The melting point, molar enthalpy and entropy of fusion for the two complexes were determined on the basis of the heat capacity measurements. Thermal decompositions of the two complexes were studied by thermogravimetric (TG) techniques and a possible mechanism for the decompositions is suggested. (C) 2002 Elsevier Science B.V. All rights reserved.
语种: 英语
WOS记录号: WOS:000180803100009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138224
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 110623, Peoples R China
2.Changde Normal Coll, Dept Chem, Changde 415000, Peoples R China

Recommended Citation:
Liu, BP,Tan, ZC,Lu, JL,et al. Low-temperature heat capacity and thermodynamic properties of crystalline [RE(Gly)(3)(H2O)(2)]Cl-3 center dot 2H(2)O (RE = Pr, Nd, Gly = Glycine)[J]. THERMOCHIMICA ACTA,2003,397(1-2):67-73.
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