DICP OpenIR
Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase
Xing, XP; Tian, ZX; Liu, HT; Tang, ZC
Source PublicationRAPID COMMUNICATIONS IN MASS SPECTROMETRY
2003
DOI10.1002/rcm.1115
Volume17Issue:15Pages:1743-1748
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Analytical ; Spectroscopy
WOS Research AreaChemistry ; Spectroscopy
WOS KeywordFLIGHT MASS-SPECTROMETER ; MOLECULAR-BEAM METHOD ; LEAD CLUSTER IONS ; CHARGE-TRANSFER ; METAL-IONS ; COMPLEXES ; PHOTODISSOCIATION ; CHEMISTRY ; ENERGIES ; ANIONS
AbstractUsing a laser ablation/inert buffer gas ion source coupled with a reflectron time-of-flight mass spectrometer, the gas-phase reactions between the IVA group element ions M+ (M = Si, Ge, Sn and Pb) and benzene seeded in argon gas were studied. In addition to the association reaction pathway (forming [M(C6H6)(x)](+), x = 1, 2, etc.), benzene was dissociated to form complex ions [M(C5H5)](+), [M(C7H5)](+) and [M(C9Hx)](+) (x = 5, 7 and 9), etc. DFT theoretical calculations indicated that, in the association products [M(C6H6)](+), the M atom is close to one carbon atom of benzene, while in most of the dissociation complexes, pentagonal structures (M/cyclopentadienyl derivatives) were formed, with the M atom situated near the fivefold axis of the five-membered ring. The bond patterns in these complexes are discussed. Copyright (C) 2003 John Wiley Sons, Ltd.
Language英语
WOS IDWOS:000184331000010
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138241
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xing, XP,Tian, ZX,Liu, HT,et al. Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2003,17(15):1743-1748.
APA Xing, XP,Tian, ZX,Liu, HT,&Tang, ZC.(2003).Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,17(15),1743-1748.
MLA Xing, XP,et al."Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 17.15(2003):1743-1748.
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