中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase
作者: Xing, XP;  Tian, ZX;  Liu, HT;  Tang, ZC
刊名: RAPID COMMUNICATIONS IN MASS SPECTROMETRY
发表日期: 2003
DOI: 10.1002/rcm.1115
卷: 17, 期:15, 页:1743-1748
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Analytical ;  Spectroscopy
研究领域[WOS]: Chemistry ;  Spectroscopy
英文摘要: Using a laser ablation/inert buffer gas ion source coupled with a reflectron time-of-flight mass spectrometer, the gas-phase reactions between the IVA group element ions M+ (M = Si, Ge, Sn and Pb) and benzene seeded in argon gas were studied. In addition to the association reaction pathway (forming [M(C6H6)(x)](+), x = 1, 2, etc.), benzene was dissociated to form complex ions [M(C5H5)](+), [M(C7H5)](+) and [M(C9Hx)](+) (x = 5, 7 and 9), etc. DFT theoretical calculations indicated that, in the association products [M(C6H6)](+), the M atom is close to one carbon atom of benzene, while in most of the dissociation complexes, pentagonal structures (M/cyclopentadienyl derivatives) were formed, with the M atom situated near the fivefold axis of the five-membered ring. The bond patterns in these complexes are discussed. Copyright (C) 2003 John Wiley Sons, Ltd.
关键词[WOS]: FLIGHT MASS-SPECTROMETER ;  MOLECULAR-BEAM METHOD ;  LEAD CLUSTER IONS ;  CHARGE-TRANSFER ;  METAL-IONS ;  COMPLEXES ;  PHOTODISSOCIATION ;  CHEMISTRY ;  ENERGIES ;  ANIONS
语种: 英语
WOS记录号: WOS:000184331000010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138241
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Xing, XP,Tian, ZX,Liu, HT,et al. Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2003,17(15):1743-1748.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xing, XP]'s Articles
 [Tian, ZX]'s Articles
 [Liu, HT]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xing, XP]‘s Articles
 [Tian, ZX]‘s Articles
 [Liu, HT]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace