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Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase
Xing, XP; Tian, ZX; Liu, HT; Tang, ZC
刊名RAPID COMMUNICATIONS IN MASS SPECTROMETRY
2003
DOI10.1002/rcm.1115
17期:15页:1743-1748
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Analytical ; Spectroscopy
研究领域[WOS]Chemistry ; Spectroscopy
关键词[WOS]FLIGHT MASS-SPECTROMETER ; MOLECULAR-BEAM METHOD ; LEAD CLUSTER IONS ; CHARGE-TRANSFER ; METAL-IONS ; COMPLEXES ; PHOTODISSOCIATION ; CHEMISTRY ; ENERGIES ; ANIONS
英文摘要Using a laser ablation/inert buffer gas ion source coupled with a reflectron time-of-flight mass spectrometer, the gas-phase reactions between the IVA group element ions M+ (M = Si, Ge, Sn and Pb) and benzene seeded in argon gas were studied. In addition to the association reaction pathway (forming [M(C6H6)(x)](+), x = 1, 2, etc.), benzene was dissociated to form complex ions [M(C5H5)](+), [M(C7H5)](+) and [M(C9Hx)](+) (x = 5, 7 and 9), etc. DFT theoretical calculations indicated that, in the association products [M(C6H6)](+), the M atom is close to one carbon atom of benzene, while in most of the dissociation complexes, pentagonal structures (M/cyclopentadienyl derivatives) were formed, with the M atom situated near the fivefold axis of the five-membered ring. The bond patterns in these complexes are discussed. Copyright (C) 2003 John Wiley Sons, Ltd.
语种英语
WOS记录号WOS:000184331000010
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被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138241
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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GB/T 7714
Xing, XP,Tian, ZX,Liu, HT,et al. Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2003,17(15):1743-1748.
APA Xing, XP,Tian, ZX,Liu, HT,&Tang, ZC.(2003).Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,17(15),1743-1748.
MLA Xing, XP,et al."Reactions between M+ (M = Si, Ge, Sn and Pb) and benzene in the gas phase".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 17.15(2003):1743-1748.
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