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题名: Facile synthesis of flavonoid 7-O-glycosides
作者: Li, M;  Han, XW;  Yu, B
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2003-08-22
DOI: 10.1021/jo034553e
卷: 68, 期:17, 页:6842-6845
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Highly regioselective removal of the 7-O-acylgroups of the peracyated flavones, isoflavones, and flavonolsyl(PhSH, imidazole, NMP) followed by effective glycosylation with glycosyl trifluoroacetimidates (BF3.Et2O) and cautious deprotection of the acyl groups under basic conditions afforded the desired 7-O-flavonoid glycosides in satisfactory yields.
关键词[WOS]: NEUTRAL CONDITIONS ;  QUERCETIN ;  GLYCOSIDES ;  GLYCOSYLATION ;  GLUCURONIDES ;  COMPLEXATION ;  DERIVATIVES ;  OXYGENATION ;  ALKYLATION ;  GLUCOSIDES
语种: 英语
WOS记录号: WOS:000184833500059
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138250
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalyst, Dalian 116023, Peoples R China

Recommended Citation:
Li, M,Han, XW,Yu, B. Facile synthesis of flavonoid 7-O-glycosides[J]. JOURNAL OF ORGANIC CHEMISTRY,2003,68(17):6842-6845.
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