DICP OpenIR
Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives
Ren, YJ; Jia, CY; Liang, P; Yang, XF; Chen, HL
KeywordSynthesis Characterization Organotin Compound
Source PublicationSYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
2003-07-01
DOI10.1081/SIM-120021941
Volume33Issue:6Pages:1115-1123
Indexed BySCI ; IC
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
Abstract1-Ethynyl-1-cycloheptanol reacts with tribenzylstannylhydride, (C6H5CH2)(3)SnH, and generates the corresponding (Z)-1-[2-(tribenzyl-stannyl)vinyl]-1-cycloheptanol. The product obtained reacts with one or two equivalents of halogen (I-2, Br-2 or ICl) to form the associated (Z)-1-[2-(dibenzylhalostannyl)vinyl]-1-cycloheptanol or (Z)-1-[2-(benzyldihalostannyl)-vinyl]-1-cycloheptanol, respectively. All compounds were characterized by elemental analyses, IR, H-1 NMR. The X-ray diffraction analysis of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol shows the presence of an intramolecular coordination of oxygen to the tin atom giving rise to a five-membered ring in which the metal exhibits a distorted trigonal-bipyramidal geometry. This may explain that a benzyl group, probably the apical one, is cleaved more easily by halogen than the vinyl substituent.
Language英语
WOS IDWOS:000183985800014
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138258
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Ren, YJ,Jia, CY,Liang, P,et al. Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,2003,33(6):1115-1123.
APA Ren, YJ,Jia, CY,Liang, P,Yang, XF,&Chen, HL.(2003).Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives.SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,33(6),1115-1123.
MLA Ren, YJ,et al."Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives".SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY 33.6(2003):1115-1123.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Ren, YJ]'s Articles
[Jia, CY]'s Articles
[Liang, P]'s Articles
Baidu academic
Similar articles in Baidu academic
[Ren, YJ]'s Articles
[Jia, CY]'s Articles
[Liang, P]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Ren, YJ]'s Articles
[Jia, CY]'s Articles
[Liang, P]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.