DICP OpenIR
Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives
Ren, YJ; Jia, CY; Liang, P; Yang, XF; Chen, HL
关键词Synthesis Characterization Organotin Compound
刊名SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
2003-07-01
DOI10.1081/SIM-120021941
33期:6页:1115-1123
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
英文摘要1-Ethynyl-1-cycloheptanol reacts with tribenzylstannylhydride, (C6H5CH2)(3)SnH, and generates the corresponding (Z)-1-[2-(tribenzyl-stannyl)vinyl]-1-cycloheptanol. The product obtained reacts with one or two equivalents of halogen (I-2, Br-2 or ICl) to form the associated (Z)-1-[2-(dibenzylhalostannyl)vinyl]-1-cycloheptanol or (Z)-1-[2-(benzyldihalostannyl)-vinyl]-1-cycloheptanol, respectively. All compounds were characterized by elemental analyses, IR, H-1 NMR. The X-ray diffraction analysis of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol shows the presence of an intramolecular coordination of oxygen to the tin atom giving rise to a five-membered ring in which the metal exhibits a distorted trigonal-bipyramidal geometry. This may explain that a benzyl group, probably the apical one, is cleaved more easily by halogen than the vinyl substituent.
语种英语
WOS记录号WOS:000183985800014
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138258
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式
GB/T 7714
Ren, YJ,Jia, CY,Liang, P,et al. Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,2003,33(6):1115-1123.
APA Ren, YJ,Jia, CY,Liang, P,Yang, XF,&Chen, HL.(2003).Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives.SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,33(6),1115-1123.
MLA Ren, YJ,et al."Synthesis and characterization of (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cycloheptanol and its benzylhalostannyl derivatives".SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY 33.6(2003):1115-1123.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Ren, YJ]的文章
[Jia, CY]的文章
[Liang, P]的文章
百度学术
百度学术中相似的文章
[Ren, YJ]的文章
[Jia, CY]的文章
[Liang, P]的文章
必应学术
必应学术中相似的文章
[Ren, YJ]的文章
[Jia, CY]的文章
[Liang, P]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。