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题名: Interference of quantized transition-state pathways in the H+D2 -> D+HD chemical reaction
作者: Dai, DX;  Wang, CC;  Harich, SA;  Wang, XY;  Yang, XM;  Chao, SD;  Skodje, RT
刊名: SCIENCE
发表日期: 2003-06-13
卷: 300, 期:5626, 页:1730-1734
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Multidisciplinary Sciences
研究领域[WOS]: Science & Technology - Other Topics
英文摘要: The collision-energy dependence of the state-resolved differential cross section at a specific backward-scattering angle for the reaction H + D-2 --> D + HD is measured with the D-atom Rydberg "tagging" time-of-flight technique. The reaction was modeled theoretically with converged quantum scattering calculations that provided physical interpretation of the observations. Oscillations in the differential cross sections in the backward-scattering direction are clearly observed and are attributed to the transition-state structures that originate from the interferences of different quantized transition-state pathways.
关键词[WOS]: DIFFERENTIAL CROSS-SECTIONS ;  HYDROGEN-EXCHANGE REACTION ;  SPECTRAL QUANTIZATION ;  H+D-2->HD+D REACTION ;  TRIPLET KETENE ;  SCATTERING ;  DYNAMICS ;  RESONANCE ;  THRESHOLDS ;  H+D-2
语种: 英语
WOS记录号: WOS:000183459700046
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138292
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China
2.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
3.Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
4.Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
5.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

Recommended Citation:
Dai, DX,Wang, CC,Harich, SA,et al. Interference of quantized transition-state pathways in the H+D2 -> D+HD chemical reaction[J]. SCIENCE,2003,300(5626):1730-1734.
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