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题名: Synthesis and potential application of novel C-2-symmetrical bis(ferrocenyl) P2N ligand
作者: Hu, XP;  Chen, HL;  Dai, HC;  Hu, XQ;  Zheng, Z
关键词: synthesis ;  C-2-symmetry ;  bis(ferrocenyl) P2N ligand ;  Pd-catalyzed allylic alkylation
刊名: CHINESE CHEMICAL LETTERS
发表日期: 2003-11-01
卷: 14, 期:11, 页:1113-1115
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A novel chiral bis(ferrocenyl) P2N ligand 1 with C-2-symmetry was synthesized through a four-step procedure from (R)-NN-dimethyl-1-ferrocenylethylamine. In a model reaction of Pd-catalyzed allylic alkylation of 1,3-diphenylprop-2-enyl acetate 6 with dimethyl malonate, good enantioselectivity (86% e.e.) was obtained.
关键词[WOS]: COMPLEXES ;  PALLADIUM(II)
语种: 英语
WOS记录号: WOS:000187579000004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138312
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Hu, XP,Chen, HL,Dai, HC,et al. Synthesis and potential application of novel C-2-symmetrical bis(ferrocenyl) P2N ligand[J]. CHINESE CHEMICAL LETTERS,2003,14(11):1113-1115.
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