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New efficient P,N,O-tridentate ligands for Ru-catalyzed asymmetric transfer hydrogenation
Dai, HC; Hu, XP; Chen, HL; Bai, CM; Zheng, Z
刊名TETRAHEDRON-ASYMMETRY
2003-06-06
DOI10.1016/S0957-4166(03)00320-3
14期:11页:1467-1472
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]RUTHENIUM(II) COMPLEXES ; AROMATIC KETONES ; STEREOSELECTIVE SYNTHESIS ; CARBONYL-COMPOUNDS ; ALCOHOLS ; PROPAN-2-OL ; ACETOPHENONE ; DERIVATIVES ; REDUCTION
英文摘要New chiral P,N,O Schiff base ligands derived from substituted salicylaldehyde and (R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine[(R,S-Fc)-PPFNH2] have been prepared and employed in ruthenium catalyzed asymmetric transfer hydrogenation of simple ketones. Up to 94% e.e. with 99% conversion was obtained when the electron-withdrawing 3,5-dinitro substituted ligand 2f was used. (C) 2003 Elsevier Science Ltd. All rights reserved.
语种英语
WOS记录号WOS:000183239900007
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138313
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Dai, HC,Hu, XP,Chen, HL,et al. New efficient P,N,O-tridentate ligands for Ru-catalyzed asymmetric transfer hydrogenation[J]. TETRAHEDRON-ASYMMETRY,2003,14(11):1467-1472.
APA Dai, HC,Hu, XP,Chen, HL,Bai, CM,&Zheng, Z.(2003).New efficient P,N,O-tridentate ligands for Ru-catalyzed asymmetric transfer hydrogenation.TETRAHEDRON-ASYMMETRY,14(11),1467-1472.
MLA Dai, HC,et al."New efficient P,N,O-tridentate ligands for Ru-catalyzed asymmetric transfer hydrogenation".TETRAHEDRON-ASYMMETRY 14.11(2003):1467-1472.
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