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题名: A comparative study of cation and anion cluster reaction products: The reaction mechanisms of lead clusters with benzene in gas phase
作者: Xing, XP;  Tian, ZX;  Liu, HT;  Tang, ZC
刊名: JOURNAL OF PHYSICAL CHEMISTRY A
发表日期: 2003-10-16
DOI: 10.1021/mrdlab.icas.ac.cn
卷: 107, 期:41, 页:8484-8491
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The cation and anion products of the reactions between lead clusters produced in the laser ablation and the benzene molecules seeded in argon were studied by high-resolution reflectron time-of-flight mass spectrometer (RTOFMS). The dominant cation products were Pb/benzene association complexes, while the dominant anion products were dehydrogenated species, [PbmCn](-), [PbmCnHk](-), etc. One important intermediate distinguished in the anion reactions was [Pb-m(C6H5)](-) product. Two conspicuously different and independent reaction mechanisms were proposed for lead cluster cations and anions, respectively.
关键词[WOS]: MOLECULAR STRUCTURE ;  CHARGE-TRANSFER ;  COMPLEXES ;  ION ;  TRANSITION ;  ETHYLENE ;  PB ;  SI
语种: 英语
WOS记录号: WOS:000185857400015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138355
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Xing, XP,Tian, ZX,Liu, HT,et al. A comparative study of cation and anion cluster reaction products: The reaction mechanisms of lead clusters with benzene in gas phase[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2003,107(41):8484-8491.
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