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题名: Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach
作者: Li, YM;  Sun, JL;  Yin, HM;  Han, KL;  He, GZ
刊名: JOURNAL OF CHEMICAL PHYSICS
发表日期: 2003-04-08
DOI: 10.1063/1.1557932
卷: 118, 期:14, 页:6244-6249
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: The 266 nm photodissociation of gaseous nitrobenzene has been studied by monitoring the NO X (2)Pi product using the single-photon laser-induced fluorescence technique. The rotational population and internal energy distributions of fragment NO product were determined. In the experiment, we only observed the rotational state distributions of the NO fragment for v(')=0. The rotational state distributions of the nascent NO photofragment can be characterized by a Boltzmann temperature of 3300+/-300 K. Ab initio calculations were performed to characterize the transition state and to determine the barrier height for the rearrangement of nitrobenzene to phenylnitrite. A clear photodissociation picture has been proposed theoretically. (C) 2003 American Institute of Physics.
关键词[WOS]: NO FRAGMENT ;  ENERGY-DISTRIBUTION ;  METHYL NITRITE ;  DISSOCIATION ;  MOLECULES ;  IONIZATION ;  ALIGNMENT ;  PATHWAYS ;  BARRIER ;  C6H5NO
语种: 英语
WOS记录号: WOS:000181834900016
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138371
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Li, YM,Sun, JL,Yin, HM,et al. Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach[J]. JOURNAL OF CHEMICAL PHYSICS,2003,118(14):6244-6249.
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