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Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach
Li, YM; Sun, JL; Yin, HM; Han, KL; He, GZ
刊名JOURNAL OF CHEMICAL PHYSICS
2003-04-08
DOI10.1063/1.1557932
118期:14页:6244-6249
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]NO FRAGMENT ; ENERGY-DISTRIBUTION ; METHYL NITRITE ; DISSOCIATION ; MOLECULES ; IONIZATION ; ALIGNMENT ; PATHWAYS ; BARRIER ; C6H5NO
英文摘要The 266 nm photodissociation of gaseous nitrobenzene has been studied by monitoring the NO X (2)Pi product using the single-photon laser-induced fluorescence technique. The rotational population and internal energy distributions of fragment NO product were determined. In the experiment, we only observed the rotational state distributions of the NO fragment for v(')=0. The rotational state distributions of the nascent NO photofragment can be characterized by a Boltzmann temperature of 3300+/-300 K. Ab initio calculations were performed to characterize the transition state and to determine the barrier height for the rearrangement of nitrobenzene to phenylnitrite. A clear photodissociation picture has been proposed theoretically. (C) 2003 American Institute of Physics.
语种英语
WOS记录号WOS:000181834900016
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138371
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Li, YM,Sun, JL,Yin, HM,et al. Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach[J]. JOURNAL OF CHEMICAL PHYSICS,2003,118(14):6244-6249.
APA Li, YM,Sun, JL,Yin, HM,Han, KL,&He, GZ.(2003).Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach.JOURNAL OF CHEMICAL PHYSICS,118(14),6244-6249.
MLA Li, YM,et al."Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach".JOURNAL OF CHEMICAL PHYSICS 118.14(2003):6244-6249.
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