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Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach
Li, YM; Sun, JL; Yin, HM; Han, KL; He, GZ
Source PublicationJOURNAL OF CHEMICAL PHYSICS
2003-04-08
DOI10.1063/1.1557932
Volume118Issue:14Pages:6244-6249
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordNO FRAGMENT ; ENERGY-DISTRIBUTION ; METHYL NITRITE ; DISSOCIATION ; MOLECULES ; IONIZATION ; ALIGNMENT ; PATHWAYS ; BARRIER ; C6H5NO
AbstractThe 266 nm photodissociation of gaseous nitrobenzene has been studied by monitoring the NO X (2)Pi product using the single-photon laser-induced fluorescence technique. The rotational population and internal energy distributions of fragment NO product were determined. In the experiment, we only observed the rotational state distributions of the NO fragment for v(')=0. The rotational state distributions of the nascent NO photofragment can be characterized by a Boltzmann temperature of 3300+/-300 K. Ab initio calculations were performed to characterize the transition state and to determine the barrier height for the rearrangement of nitrobenzene to phenylnitrite. A clear photodissociation picture has been proposed theoretically. (C) 2003 American Institute of Physics.
Language英语
WOS IDWOS:000181834900016
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138371
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Li, YM,Sun, JL,Yin, HM,et al. Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach[J]. JOURNAL OF CHEMICAL PHYSICS,2003,118(14):6244-6249.
APA Li, YM,Sun, JL,Yin, HM,Han, KL,&He, GZ.(2003).Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach.JOURNAL OF CHEMICAL PHYSICS,118(14),6244-6249.
MLA Li, YM,et al."Photodissociation of nitrobenzene at 266 nm: Experimental and theoretical approach".JOURNAL OF CHEMICAL PHYSICS 118.14(2003):6244-6249.
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