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题名: Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage
作者: Xing, XP;  Liu, HT;  Tang, ZC
刊名: PHYSCHEMCOMM
发表日期: 2003-04-22
DOI: 10.1039/b302761a
卷: 6, 页:32-35
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: This article reports on the generation of [M-m-phenyl](-) (M = Mn-Cu) complexes, which are very rare cases in chemistry. Experimental results showed that the typical cation products for the reactions of all 3d transition metal clusters (Sc-Cu) with benzene were different [M-m(C6H6)(n)](+) (M = Sc-Cu) species, while the typical anion products for the late 3d transition metals were [M-m-C6H5](-) (M = Mn-Cu) complexes. Their formation mechanisms, which involve anion metal clusters inducing a selective benzene C - H cleavage in the gas phase, were proposed.
关键词[WOS]: FLIGHT MASS-SPECTROMETER ;  PHOTOELECTRON-SPECTROSCOPY ;  CHARGE-TRANSFER ;  PHOTODISSOCIATION ;  CHEMISORPTION
语种: 英语
WOS记录号: WOS:000182473600001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138372
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Ctr Mol Sci, Beijing 100080, Peoples R China

Recommended Citation:
Xing, XP,Liu, HT,Tang, ZC. Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage[J]. PHYSCHEMCOMM,2003,6:32-35.
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