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Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage
Xing, XP; Liu, HT; Tang, ZC
刊名PHYSCHEMCOMM
2003-04-22
DOI10.1039/b302761a
6页:32-35
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]FLIGHT MASS-SPECTROMETER ; PHOTOELECTRON-SPECTROSCOPY ; CHARGE-TRANSFER ; PHOTODISSOCIATION ; CHEMISORPTION
英文摘要This article reports on the generation of [M-m-phenyl](-) (M = Mn-Cu) complexes, which are very rare cases in chemistry. Experimental results showed that the typical cation products for the reactions of all 3d transition metal clusters (Sc-Cu) with benzene were different [M-m(C6H6)(n)](+) (M = Sc-Cu) species, while the typical anion products for the late 3d transition metals were [M-m-C6H5](-) (M = Mn-Cu) complexes. Their formation mechanisms, which involve anion metal clusters inducing a selective benzene C - H cleavage in the gas phase, were proposed.
语种英语
WOS记录号WOS:000182473600001
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被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138372
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Ctr Mol Sci, Beijing 100080, Peoples R China
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Xing, XP,Liu, HT,Tang, ZC. Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage[J]. PHYSCHEMCOMM,2003,6:32-35.
APA Xing, XP,Liu, HT,&Tang, ZC.(2003).Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage.PHYSCHEMCOMM,6,32-35.
MLA Xing, XP,et al."Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage".PHYSCHEMCOMM 6(2003):32-35.
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