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Studies on electrochemical stability of room temperature ionic liquids
Yang, JZ; Jin, Y; Cao, YH; Sun, LX; Tan, ZC
关键词Room Temperature Ionic Liquid Electrochemical Stability Bpbf4 Bmibf4 Emise
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
2004-09-01
25期:9页:1733-1735
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]THERMODYNAMICS
英文摘要In this paper three air and water-stable room temperature ionic liquids (RTILs): N-butylpyridinium tetrafluoroborate(BPBF4), 1-butyl-3-methylimidazolium tetrafluoroborate(BMIBF4), and 1-ethyl-3-methylimidazolium ethyl sulfate(EMISE) were synthesized. Their electrochemical windows were measured by cyclic voltammetry at 303. 15-343. 15 K. The cyclic voltammograms show the order of windows which represent the electrochemical stability of RTIL is: BPBF4BMI+ \ - 0.95 V \ >BP+ \0.02 V \. It is very interesting that while the oxidative limit of anion BF4- and the reductive limit of all the cations reduce with the increase of temperature, but the oxidative limit of anion SE- increases.
语种英语
WOS记录号WOS:000224014600037
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被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138405
专题中国科学院大连化学物理研究所
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Yang, JZ,Jin, Y,Cao, YH,et al. Studies on electrochemical stability of room temperature ionic liquids[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(9):1733-1735.
APA Yang, JZ,Jin, Y,Cao, YH,Sun, LX,&Tan, ZC.(2004).Studies on electrochemical stability of room temperature ionic liquids.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(9),1733-1735.
MLA Yang, JZ,et al."Studies on electrochemical stability of room temperature ionic liquids".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.9(2004):1733-1735.
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