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Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst
Wang, F; Yang, GY; Zhang, W; Wu, WH; Xu, J
关键词Copper P-cresol Heterogeneous Catalysis P-hydroxybenzaldehyde Manganese
刊名ADVANCED SYNTHESIS & CATALYSIS
2004-05-01
DOI10.1002/adsc.200303226
346期:6页:633-638
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]LIQUID-PHASE OXIDATION ; REIMER-TIEMANN REACTION ; SATURATED-HYDROCARBONS ; ONE-STEP ; AIR ; ACTIVATION ; COMPLEXES ; PHENOLS ; COPPER ; SIEVES
英文摘要A high-yield synthesis of p-hydroxybenzaldehyde from p-cresol and molecular oxygen was achieved over a CuMn-oxide supported carbon catalyst. The reaction parameters such as pressure, stirring speed, reaction temperature, solvent, and the amount of sodium hydroxide in the reaction media were optimized. As a result, a high conversion of p-cresol (99%) and a high selectivity to p-hydroxybenzaldehyde (96%) were realized at the same time. Catalyst separation and recycling tests clearly showed that the reaction proceeded on the heterogeneous catalyst but not on dissolved species.
语种英语
WOS记录号WOS:000222129300008
引用统计
被引频次:33[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138447
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wang, F,Yang, GY,Zhang, W,et al. Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst[J]. ADVANCED SYNTHESIS & CATALYSIS,2004,346(6):633-638.
APA Wang, F,Yang, GY,Zhang, W,Wu, WH,&Xu, J.(2004).Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst.ADVANCED SYNTHESIS & CATALYSIS,346(6),633-638.
MLA Wang, F,et al."Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst".ADVANCED SYNTHESIS & CATALYSIS 346.6(2004):633-638.
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