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Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations
Wang, ML; Han, KL; He, GZ
刊名JOURNAL OF PHYSICAL CHEMISTRY A
1998-12-10
102期:50页:10204-10210
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]STATE-RESOLVED STEREODYNAMICS ; CHEMILUMINESCENT REACTION ; ANGULAR-CORRELATIONS ; EXCHANGE-REACTIONS ; CROSS-SECTIONS ; ALIGNMENT ; ORIENTATION ; MOLECULES ; DISTRIBUTIONS ; MAGNITUDE
英文摘要In cases of light-heavy-light (LHL), light-light-heavy (LLH), and light-heavy-heavy (LHH) mass combinations, the product rotational polarization is reported using the quasiclassical trajectory method in the photoinitiated bimolecular reaction A + BC --> AB + C on attractive, mixed, and repulsive surfaces. Four polarization-dependent differential cross sections (PDDCS) which are sensitive to many photoinitiated bimolecular reaction experiments are presented. Furthermore, the dihedral angle distribution P(phi(r)) characterizing the K-K'-J' correlation and the distribution of angle between K and J' P(theta(r)) are discussed. Finally, the angular distributions P(theta(r),phi(r)) of product rotational vectors in the form of polar plots in theta(r) and phi(r) are shown.
语种英语
WOS记录号WOS:000077543700003
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被引频次:216[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138465
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Wang, ML,Han, KL,He, GZ. Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations[J]. JOURNAL OF PHYSICAL CHEMISTRY A,1998,102(50):10204-10210.
APA Wang, ML,Han, KL,&He, GZ.(1998).Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations.JOURNAL OF PHYSICAL CHEMISTRY A,102(50),10204-10210.
MLA Wang, ML,et al."Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations".JOURNAL OF PHYSICAL CHEMISTRY A 102.50(1998):10204-10210.
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