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Electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode
Jiang, JH; Chen, L; Wu, BL; Zhai, RS
关键词Solid Polymer Electrolyte Nafion Membrane Electrochemical Reduction Nitrobenzene Aniline
刊名ACTA PHYSICO-CHIMICA SINICA
1998-08-01
DOI10.3866/PKU.WHXB19980807
14期:8页:704-708
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ORGANIC ELECTROCHEMISTRY ; SPE METHOD
英文摘要The electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode was investigated. The 1 eduction product was only aniline. The high selectivity was related to the weak acid medium at the electrode/Nafion interface and the slow diffusion of intermediates in the membrane. The electrochemical process was controlled by the diffusion of some species, the current efficiency for aniline decreased with the current density and was dependent upon the dissolution of nitrobenzene in the membrane.
语种英语
WOS记录号WOS:000075809200007
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138474
专题中国科学院大连化学物理研究所
作者单位1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Jiang, JH,Chen, L,Wu, BL,et al. Electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode[J]. ACTA PHYSICO-CHIMICA SINICA,1998,14(8):704-708.
APA Jiang, JH,Chen, L,Wu, BL,&Zhai, RS.(1998).Electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode.ACTA PHYSICO-CHIMICA SINICA,14(8),704-708.
MLA Jiang, JH,et al."Electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode".ACTA PHYSICO-CHIMICA SINICA 14.8(1998):704-708.
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