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题名: Electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode
作者: Jiang, JH;  Chen, L;  Wu, BL;  Zhai, RS
关键词: solid polymer electrolyte ;  nafion membrane ;  electrochemical reduction ;  nitrobenzene ;  aniline
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1998-08-01
DOI: 10.3866/PKU.WHXB19980807
卷: 14, 期:8, 页:704-708
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode was investigated. The 1 eduction product was only aniline. The high selectivity was related to the weak acid medium at the electrode/Nafion interface and the slow diffusion of intermediates in the membrane. The electrochemical process was controlled by the diffusion of some species, the current efficiency for aniline decreased with the current density and was dependent upon the dissolution of nitrobenzene in the membrane.
关键词[WOS]: ORGANIC ELECTROCHEMISTRY ;  SPE METHOD
语种: 英语
WOS记录号: WOS:000075809200007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138474
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Jiang, JH,Chen, L,Wu, BL,et al. Electrochemical reduction of nitrobenzene on the Cu/C-Nafion composite electrode[J]. ACTA PHYSICO-CHIMICA SINICA,1998,14(8):704-708.
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