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Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene
Liu, CQ; Xu, Y; Liao, SJ; Yu, DR
关键词Polymer-supported Bimetallic Catalyst Synergic Effect 1-octene Hydrogenation Isomerization
刊名JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
1999-12-15
149期:1-2页:119-123
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]HOMOGENEOUS MULTIMETALLIC CATALYSTS ; SELECTIVE HYDROGENATION ; PALLADIUM-RUTHENIUM ; BUTADIENE ; CLUSTERS ; GAS
英文摘要The catalytic properties of the bimetallic catalysts for the hydrogenation and isomerization of 1-octene were investigated. The PVP-PdCl2-1/2Co(OAc)(2) bimetallic catalyst reduced by NaBH4 exhibited a remarkable bimetallic synergic effect under mild conditions of 40 degrees C and 0.1 MPa. The maximum turnover frequency (TOFmax, mol H-2/mol Pd min) can be nearly doubled compared with that of the reaction catalyzed by the monometallic catalyst, and simultaneously the isomerization:of 1-octene to 2-octene and 3-octene was inhibited significantly. (C) 1999 Elsevier Science B.V. All rights reserved.
语种英语
WOS记录号WOS:000084148900012
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被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138537
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Liu, CQ,Xu, Y,Liao, SJ,et al. Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,149(1-2):119-123.
APA Liu, CQ,Xu, Y,Liao, SJ,&Yu, DR.(1999).Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,149(1-2),119-123.
MLA Liu, CQ,et al."Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 149.1-2(1999):119-123.
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