中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene
作者: Liu, CQ;  Xu, Y;  Liao, SJ;  Yu, DR
关键词: polymer-supported bimetallic catalyst ;  synergic effect ;  1-octene ;  hydrogenation ;  isomerization
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 1999-12-15
卷: 149, 期:1-2, 页:119-123
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The catalytic properties of the bimetallic catalysts for the hydrogenation and isomerization of 1-octene were investigated. The PVP-PdCl2-1/2Co(OAc)(2) bimetallic catalyst reduced by NaBH4 exhibited a remarkable bimetallic synergic effect under mild conditions of 40 degrees C and 0.1 MPa. The maximum turnover frequency (TOFmax, mol H-2/mol Pd min) can be nearly doubled compared with that of the reaction catalyzed by the monometallic catalyst, and simultaneously the isomerization:of 1-octene to 2-octene and 3-octene was inhibited significantly. (C) 1999 Elsevier Science B.V. All rights reserved.
关键词[WOS]: HOMOGENEOUS MULTIMETALLIC CATALYSTS ;  SELECTIVE HYDROGENATION ;  PALLADIUM-RUTHENIUM ;  BUTADIENE ;  CLUSTERS ;  GAS
语种: 英语
WOS记录号: WOS:000084148900012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138537
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Liu, CQ,Xu, Y,Liao, SJ,et al. Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,149(1-2):119-123.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Liu, CQ]'s Articles
 [Xu, Y]'s Articles
 [Liao, SJ]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Liu, CQ]‘s Articles
 [Xu, Y]‘s Articles
 [Liao, SJ]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace