中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR
作者: Li, Q;  Li, HZ;  Kong, F
关键词: oxalyl chloride ;  2,3-butanedione ;  UV photolysis ;  IR emission spectrum
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1999-03-01
DOI: 10.3866/PKU.WHXB19990312
卷: 15, 期:3, 页:259-264
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The photodissociation of oxalyl chloride anti 2,3-butanedione at 193nm and 248nm have been studied by Time-resolved FTIR emission spectroscopy, The IR fluorescence emission was observed and the rotational and vibrational populations ai the CO product were obtained. It is suggested that the photolysis mechanism is two RCO radicals formed via a fission of C-C bond, followed by a decomposition of the RCO intermediate to vibrationally excited CO(v) and R radical.
关键词[WOS]: VIBRATIONAL-STATE DISTRIBUTIONS ;  EMISSION-SPECTROSCOPY ;  193 NM ;  ROTATIONAL-STATE ;  ACETONE ;  PHOTODISSOCIATION ;  DYNAMICS
语种: 英语
WOS记录号: WOS:000079433200012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138544
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Li, Q,Li, HZ,Kong, F. UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR[J]. ACTA PHYSICO-CHIMICA SINICA,1999,15(3):259-264.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li, Q]'s Articles
 [Li, HZ]'s Articles
 [Kong, F]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li, Q]‘s Articles
 [Li, HZ]‘s Articles
 [Kong, F]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace