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题名: Molecule imprinting chiral stationary phase
作者: Meng, ZH;  Zhou, LM;  Wang, JF;  Wang, QH;  Zhu, DQ
刊名: BIOMEDICAL CHROMATOGRAPHY
发表日期: 1999-10-01
卷: 13, 期:6, 页:389-393
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Life Sciences & Biomedicine ;  Physical Sciences
类目[WOS]: Biochemical Research Methods ;  Biochemistry & Molecular Biology ;  Chemistry, Analytical ;  Pharmacology & Pharmacy
研究领域[WOS]: Biochemistry & Molecular Biology ;  Chemistry ;  Pharmacology & Pharmacy
英文摘要: Molecule imprinting polymers (MIPs) with high chiral selectivity for N-alpha-protected amino acids were synthesized in polar solvent using acrylamide (AM) or combined functional monomer methacrylic acid (MAA) + vinyl pyridine (VP). Factors that influence the chiral selectivity of MIPs and mechanisms of the chiral recognition process were investigated. It was found that the rigid structure and the polar functional group of the print molecule were very important for the chiral selectivity of MIPs. For MIPs made using a combined functional monomer, ionic and hydrophobic interaction may be responsible for the chiral recognition process in aqeous media. The number of binding sites on MIPs and dissociation constants for the complex of enantiomers and MIPs were determined by frontal chromatography analysis. Copyright (C) 1999 John Wiley & Sons, Ltd.
关键词[WOS]: RESOLUTION
语种: 英语
WOS记录号: WOS:000082935900003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138577
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China

Recommended Citation:
Meng, ZH,Zhou, LM,Wang, JF,et al. Molecule imprinting chiral stationary phase[J]. BIOMEDICAL CHROMATOGRAPHY,1999,13(6):389-393.
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