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The state of Rh during the partial oxidation of methane into synthesis gas
Tian, ZJ; Dewaele, O; Marin, GB
KeywordMethane Partial Oxidation Synthesis Gas Drifts Supported Rh Catalyst
Source PublicationCATALYSIS LETTERS
1999
Volume57Issue:1-2Pages:9-17
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordREACTION-MECHANISM ; CO CHEMISORPTION ; METAL CATALYSTS ; RHODIUM ; RH/AL2O3 ; TRANSIENT ; TOPOLOGY
AbstractThe partial oxidation of methane to synthesis gas over an alpha-Al2O3- and gamma-Al2O3-supported Rh catalyst has been studied at atmospheric pressure using in situ DRIFTS between 823 and 973 K. A surface intermediate species with IR band at 2000 cm(-1), correlating with the CO formation, was observed during the partial oxidation. DRIFT spectra of adsorbed CO at 323 K were used to study the state of Rh during the partial oxidation. The state of Rh at 973 K is proposed to be a matrix of metallic rhodium with clusters of partially reduced oxide phase with isolated Rh+ atoms dispersed on the support. Rh oxide with Rh+ cations is the state of Rh during partial oxidation of methane at 823 K.
Language英语
WOS IDWOS:000078792000002
Citation statistics
Cited Times:30[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138594
Collection中国科学院大连化学物理研究所
Affiliation1.State Univ Ghent, Petrochem Tech Lab, B-9000 Ghent, Belgium
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Tian, ZJ,Dewaele, O,Marin, GB. The state of Rh during the partial oxidation of methane into synthesis gas[J]. CATALYSIS LETTERS,1999,57(1-2):9-17.
APA Tian, ZJ,Dewaele, O,&Marin, GB.(1999).The state of Rh during the partial oxidation of methane into synthesis gas.CATALYSIS LETTERS,57(1-2),9-17.
MLA Tian, ZJ,et al."The state of Rh during the partial oxidation of methane into synthesis gas".CATALYSIS LETTERS 57.1-2(1999):9-17.
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