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题名: Multiphoton ionization and ab initio calculation studies of the hydrogen-bonded clusters C4H5N-(H2O)(n)
作者: Li, Y;  Liu, XH;  Wang, XY;  Lou, NQ
刊名: JOURNAL OF PHYSICAL CHEMISTRY A
发表日期: 1999-04-15
卷: 103, 期:15, 页:2572-2579
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The multiphoton ionization of the hydrogen-bonded clusters C4H5N-(H2O)(n) was studied using a time-of-flight mass spectrometer at the laser wavelengths of 355 and 532 nm. At both wavelengths, a series of C4H5N(H2O)(n)(+) and the protonated C4H5N-(H2O)(n)H+ were obtained. The two-photon resonance ionization processes at 355 nm make this wavelength produce obviously more abundant ions of pyrrole and the clusters than 532 nm. Ab initio calculations show that in the protonated products, the proton prefers to link with the alpha-C of pyrrole rather than with the N atom. The production of the protonated products requires an intracluster proton transfer reaction. The protonated products obtained at 532 nm are suggested to arise from an intracluster penning ionization or a charge transfer process. The abnormally higher intensities of C4H4N-(H2O)(n)(+) (n greater than or equal to 1) than those of C4H4N+ are attributed to the stabilization effects of the cluster formation on the dissociation products C4H4N+ of the pyrrole molecule.
关键词[WOS]: PHASE UNIMOLECULAR DECOMPOSITION ;  PROTON-TRANSFER REACTIONS ;  CARBON-DIOXIDE CLUSTERS ;  DER-WAALS CLUSTERS ;  GAS-PHASE ;  AMMONIA CLUSTERS ;  METASTABLE DECOMPOSITION ;  PHOTOELECTRON-SPECTRA ;  CHEMICAL-REACTIONS ;  BINARY CLUSTERS
语种: 英语
WOS记录号: WOS:000079933500013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138610
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Li, Y,Liu, XH,Wang, XY,et al. Multiphoton ionization and ab initio calculation studies of the hydrogen-bonded clusters C4H5N-(H2O)(n)[J]. JOURNAL OF PHYSICAL CHEMISTRY A,1999,103(15):2572-2579.
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