DICP OpenIR
Enthalpy-entropy compensation effect in gas chromatographic enantiomeric separation
Zhou, LM; Nie, MY; Wang, QH; Zhu, DQ; Shen, HQ
关键词Enthalpy-entropy Compensation Effect Chiral Separation Gc Modified Cd-csp Diamide Csp
刊名CHINESE JOURNAL OF CHEMISTRY
1999-07-01
17期:4页:363-376
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]AMINO-ACID ENANTIOMERS ; STATIONARY-PHASE ; MODIFIED CYCLODEXTRINS ; RESOLUTION ; DERIVATIVES ; RECOGNITION ; BEHAVIOR ; ALCOHOLS
英文摘要In this paper, the enthalpy-entropy compensation effect in the enantiomeric separation by modified cyclodextrins (CD) and diamide chiral stationary phase (CSP) gas chromatography was investigated using the method of plotting Delta(Delta H) versus Delta(Delta G)(Thm) combined with t-test statistic analysis. The investigated racemates cover alpha-phenylethylamine and its analogs, 2-alkylamines, chiral acyclic alcohols, halogenated arylethanediol-1, 2-diperfluoropropionates, amino acid and its analogs, and two series of compounds containing chloro and bromo substituents. From the compensation analysis results, the effects of the diluent composition in the investigated chiral stationary phases, the size and. the modified groups on investigated cyclodextrins, the derivatization methods and the groups attached to the stereocenters on enantiomeric separation mechanisms were all discussed.
语种英语
WOS记录号WOS:000082209300008
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138627
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
推荐引用方式
GB/T 7714
Zhou, LM,Nie, MY,Wang, QH,et al. Enthalpy-entropy compensation effect in gas chromatographic enantiomeric separation[J]. CHINESE JOURNAL OF CHEMISTRY,1999,17(4):363-376.
APA Zhou, LM,Nie, MY,Wang, QH,Zhu, DQ,&Shen, HQ.(1999).Enthalpy-entropy compensation effect in gas chromatographic enantiomeric separation.CHINESE JOURNAL OF CHEMISTRY,17(4),363-376.
MLA Zhou, LM,et al."Enthalpy-entropy compensation effect in gas chromatographic enantiomeric separation".CHINESE JOURNAL OF CHEMISTRY 17.4(1999):363-376.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhou, LM]的文章
[Nie, MY]的文章
[Wang, QH]的文章
百度学术
百度学术中相似的文章
[Zhou, LM]的文章
[Nie, MY]的文章
[Wang, QH]的文章
必应学术
必应学术中相似的文章
[Zhou, LM]的文章
[Nie, MY]的文章
[Wang, QH]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。