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Oxidation of trimethylphenol catalyzed by aqueous soluble oxygen carriers
Zhou, N; Xi, ZW; Cao, GY; Zhang, XF; Hai, XD
关键词Trimethylquinone Oxygen Carrier Water Soluble Biphase System
刊名OXIDATION COMMUNICATIONS
1999
22期:4页:527-531
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]DIOXYGEN
英文摘要Oxygen carriers such as metalloporphyrin, metallophthalocyanine and cobalt Schiff base etc., were effective catalysts for oxidation of phenols to quinones. The influence of the aqueous soluble oxygen carriers on the oxidation of trimethylphenol was investigated under various conditions. In homogeneous reaction system, DMF was a good solvent in which high yield was achieved; with addition of NaOH in homogeneous system, the conversion increased and the selectivity decreased; in water-oil biphase system, condensation product was readily produced; after the reaction being carried out in DMF + toluene homogeneous system, the catalyst could be extracted with dilute Na2CO3 solution.
语种英语
WOS记录号WOS:000084540600007
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138634
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhou, N,Xi, ZW,Cao, GY,et al. Oxidation of trimethylphenol catalyzed by aqueous soluble oxygen carriers[J]. OXIDATION COMMUNICATIONS,1999,22(4):527-531.
APA Zhou, N,Xi, ZW,Cao, GY,Zhang, XF,&Hai, XD.(1999).Oxidation of trimethylphenol catalyzed by aqueous soluble oxygen carriers.OXIDATION COMMUNICATIONS,22(4),527-531.
MLA Zhou, N,et al."Oxidation of trimethylphenol catalyzed by aqueous soluble oxygen carriers".OXIDATION COMMUNICATIONS 22.4(1999):527-531.
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