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题名: Polymer-supported palladium-based bimetallic catalysts for the oxidative carbonylation of aniline
作者: Wan, BS;  Liao, SJ;  Yu, DR
关键词: PVP-PdCl2-MnCl2 ;  bimetallic catalyst ;  oxidative carbonylation ;  synergic effect ;  ethyl N-phenylcarbamate
刊名: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
发表日期: 1999-06-01
卷: 20, 期:6, 页:963-964
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Polymer-supported bimetallic catalyst PVP-PdCl2-MnCl2 [PVP = poly(N-vinyl-2-pyrrolidone] exhibits a high activity and selectivity for the oxidative carbonylation of aniline to carbamate ester under atmospheric pressure[V(CO)/V(O-2) = 10/1]. A remarkable bimetallic synergic effect in PVP-PdCl2-MXn (M: second transition metal) gives rise to an obvious increase in the conversion and selectivity for the reaction in the presence of a base (NaOAc), Among the M components tested, Mn-Pd exhibits the strongest synergic effect.
关键词[WOS]: REGIOSELECTIVE HYDROESTERIFICATION ;  STYRENE
语种: 英语
WOS记录号: WOS:000080941600034
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138635
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wan, BS,Liao, SJ,Yu, DR. Polymer-supported palladium-based bimetallic catalysts for the oxidative carbonylation of aniline[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1999,20(6):963-964.
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