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Polymer-supported palladium-based bimetallic catalysts for the oxidative carbonylation of aniline
Wan, BS; Liao, SJ; Yu, DR
关键词Pvp-pdcl2-mncl2 Bimetallic Catalyst Oxidative Carbonylation Synergic Effect Ethyl N-phenylcarbamate
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
1999-06-01
20期:6页:963-964
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]REGIOSELECTIVE HYDROESTERIFICATION ; STYRENE
英文摘要Polymer-supported bimetallic catalyst PVP-PdCl2-MnCl2 [PVP = poly(N-vinyl-2-pyrrolidone] exhibits a high activity and selectivity for the oxidative carbonylation of aniline to carbamate ester under atmospheric pressure[V(CO)/V(O-2) = 10/1]. A remarkable bimetallic synergic effect in PVP-PdCl2-MXn (M: second transition metal) gives rise to an obvious increase in the conversion and selectivity for the reaction in the presence of a base (NaOAc), Among the M components tested, Mn-Pd exhibits the strongest synergic effect.
语种英语
WOS记录号WOS:000080941600034
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138635
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Wan, BS,Liao, SJ,Yu, DR. Polymer-supported palladium-based bimetallic catalysts for the oxidative carbonylation of aniline[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1999,20(6):963-964.
APA Wan, BS,Liao, SJ,&Yu, DR.(1999).Polymer-supported palladium-based bimetallic catalysts for the oxidative carbonylation of aniline.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,20(6),963-964.
MLA Wan, BS,et al."Polymer-supported palladium-based bimetallic catalysts for the oxidative carbonylation of aniline".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 20.6(1999):963-964.
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