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题名: Effect of rigidity of the imprinted molecule to chiral separation of molecular imprinting chiral stationary phase
作者: Wang, JF;  Zhou, LM;  Meng, ZH;  Liu, XL;  Wang, QH;  Zhu, DQ
关键词: molecular imprinting chiral stationary phase ;  combined functional monomers ;  amino acid derivatives
刊名: CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
发表日期: 1999-12-01
卷: 27, 期:12, 页:1420-1423
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical
研究领域[WOS]: Chemistry
英文摘要: Molecular imprinting polymers (MIPs) against Cbz-L-Ser, Cbz-L-Ala and Cbz-L-Pro utilizing acrylamide plus 2-vinylpyridine as combined basic functional monomers were prepared and evaluated in high-performance liquid chromatography mode. Less rigid molecules, Cbz-L-Ser and Cbz-L-Ala, which have suitable chemical functional groups to interact with the functional monomers were successfully imprinted and the MIPs shaved excellent chiral separation ability to the imprinted enantiomer. It was found that not the rigidity but the suitable chemical functional groups of the imprinted molecule to interact with the functional monomers was a key problem to realize molecular imprinting.
关键词[WOS]: POLYMERS
语种: 英语
WOS记录号: WOS:000084530900013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138645
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
2.Acad Mil Med Sci, Beijing 100850, Peoples R China

Recommended Citation:
Wang, JF,Zhou, LM,Meng, ZH,et al. Effect of rigidity of the imprinted molecule to chiral separation of molecular imprinting chiral stationary phase[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,1999,27(12):1420-1423.
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